Item 08 - Approve the Modified Final Design for the Comal Pocket Park AIPP Project

Arts Commission – Jan. 29, 2024

Item 08 - Approve the Modified Final Design for the Comal Pocket Park AIPP Project — original pdf

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Date: From: Copy: Modified Final Design Memo to File January 29, 2024 Artist and Austin Art in Public Places Staff: Contracted Artist Dana Perrotti, Program Manager Constance White, and Project Coordinator Ryan Runcie Arts Commission: Panel Chair Celina Zisman, Vice Chair Heidi Schmalbach, and Panel members Monica Maldonado, Felipe Garza, Gina Houston, Michael Vernusky, Acia Gray, Faiza Kracheni, Amy Mok, Nagavalli Medicharla Subject: Comal Pocket Park AIPP Project Background: The AIPP Panel first approved the Final Design proposal for the Comal Pocket Park AIPP Project on September 18, 2023. The artist seeks approval for modifications to the artwork color palette and iconography used in the ceramic tile mural installation. September 18, 2023 Arts Commission Approval A motion to approve items 10 – 15 on consent on Commissioner Gray's motion, Commissioner Mok second on a 9-0 vote with Commissioners Maldonado and Csillagi absent. Concept Narrative: To reflect the Mexican and Latin American history and heritage of the park, the design inspiration comes from Milagros, or folk charms representing prayers, wishes, and healing. These symbols traditionally are made of metal and used as offerings or carried as protection. The charms range from body parts (eyes, hearts, legs: to represent wishes to heal ailments), to farm animals (hens, bulls, sheep: to represent either abundance on the farm or concepts like mothering/fathering/togetherness), to houses (to wish for blessings on the home). The theme of Milagros will inform the design for the installation at Parque Comal. Custom stoneware tiles will be fabricated with relief designs inspired by traditional Milagros symbols and community engagement. Artwork Narrative: The tiles will be installed on the North and South cinder block walls that frame the Parque Comal entrance archway. Dimensions of the north retaining wall are 23.25 in. x 183.75 in. The dimensions of the south retaining wall are 23.25 in. x 293.5 in. No changes will be made to the existing arch. Tiles will be made from heavily grogged mid-ﬁre stoneware from Standard Clay, Sculpture Body #420 (30 percent grog content, ﬁred to cone 6). The absorp�on rate of the material at cone 6 is 2%, with a maximum of 3 percent, which is required for outdoor installa�on. The ar�st will make custom glazes, tes�ng the “ﬁt” of the glaze to the clay body to ensure that a proper seal is formed (ie, no crazing, or crackling of the glaze surface). Tes�ng will involve submerging ﬁred test �les in boiling water and directly transferring the hot �les to a freezing environment to test the materials at both extremes and simulate more wear and exposure. Tiles will be set on the cinderblock wall at Parque Comal with thin-set and a grout stain to be complementary to the existing installation. An an�-graﬃ� sealant will be applied to the completed installa�on. Chalmers Court, Milagros Tile Making, May 2023 Guerrero Senior Center, Milagros Tile Making, April 2023 Mendez Recreation Center, Milagros Tile Making April 2023 Results of Community Engagement • Atended Residents’ Mee�ng at the Chalmer’s Court, located one block from Parque Comal. Introduced myself, the project, and heard feedback from the residents. • Tile Making Workshop at Mendez Recrea�on Center to make art with their a�er-school program. 20 youth par�cipants created relief �les from leather-hard clay to create their own Milagros. • Tile Making Workshop at the Conley-Guerrero Senior Center. 13 par�cipants created their own Milagros relief �les from leather-hard clay. We discussed themes of the project and deeper meanings of their art. to make art with March 2023 April 2023 May 2023 • Tile Making Workshop at the Calmer’s Court to make art with residents. 20 par�cipants carved and glazed personal Milagro �les. Par�cipants were most interested to create Milagros that were in the following categories: • Animals • Body Parts and the Human Figure • Natural Elements such as ﬂowers and trees • Travel This informed which Milagros I chose to include in the Final Tile Design. LOTS 7 -12, BLOCK 3 PECK SUBDMSION OlfTLOT 4 , DMSION •o• OF VOL S, PAGE 551 D.R.T.C.TX. I I I I I I I I I I I I I I I !' IIi; I I / gt �;: /;; O" §�� (EXISTING TURF TO REMAIN ) I I I ..... � � , .......... CONCRETE S RIGHT-Oi'=:WA IDEWALK (5' SEE D � -.....__ , > _ 7 • EZ-FLOW DRAN PIP LONG; SEE Sf�IFlCA AIPP Project in RED is outlined location - LOCATE ' ' , GUTTER; SEE CM -- LEGEND = UI: - - - - ��srfucTION @(BISTING TREES CRZ & HCRZ) './ I v/ _ ELOCAfED WATER �ETER· SHE :;: / oiRm RAMP; SEE � DETAIL 432S-3H O WER POLE '(STING P ~ ----- TO REMAIN , .:::_ r CHAIN LINK FENCE I , ......_ -........__ , ,..._-.,,...�--�,--.... I ........................ . - -- I I � ....._ -----.__, ---- PA ORNAMENTAL FENCE\ ......-., --...J�J PlANTING AREA SCALE 16 ' O' 32' NORTI-1 � / Milagros Relief Tiles, 7.5”x7.5” each + ½” Grout Border (Without Color–to emphasize relief detail) North Wall: 23.25”x183.75” South Wall Installation Dimensions: 23.25” x 293.5” 23.5" x187.5" 23.5" x 293.5" *Modification for approval Taking the purples and blues from the top of the arch to create a color scheme that will anchor the archway, connecting top and bottom in a beautiful way! Tile: 7.5” width x 7.5” length x 0.5” depth Relief: 0.5” above surface -Standard Clay, Sculpture body #420 (30 % grog content ﬁred to cone 6) List of Materials Ceramic Tiles and Glazes EPK Kaolin (Edgar Clay) Custom mixed glazes - Custer Feldspar Spodumene - Silica - Talc - - EPK - Ball Clay 0M4 Frit 3134 - - Frit 3195 - Wollastonite Mason Stains - Chrome �n pink sphene – Alpine Rose - Chrome �n pink sphene – Crimson - Cobalt Silicate Blue Olivine – Mazurine and Pansy Purple - Cobalt Zinc Aluminate Blue Spinel – Vivid Blue - Cobalt Tin Alumina Blue Spinel – Delphinium Blue Installa�on Thin Tile mortar Laticrete Multimax Lite - Strong exterior, large and heavy tile mortar - 600 PSI shear strength Spectalock Pro Premium Grout - Epoxy based grout Sealant World’s best an�-graﬃ� sealant Conservation Review Form CITY OF AUSTIN AIPP Exhibit F Information captured in this form will help expedite the conservation review process, which aims to address the following considerations: 1) Durability of Materials 2) Appropriateness of Fabrication Methods 3) Relationship to Site/Context 4) Installation and Site Preparation 5) Maintenance Needs Artist(s): Phone: Email: Title of AIPP Project: Title of Artwork: AIPP Project Manager: Date: Assuming best maintenance practices, what is the life expectancy of this work? List ALL materials and components to be used in the creation of this piece (be specific): Describe any coatings or sealants to be used (be specific): Provide contact information for the fabricator(s) and a description of their services on this project: Rev. Jan 2013 Page | 1 Conservation Review Form CITY OF AUSTIN AIPP Describe the methods and/or processes used in fabrication, in order of their use in the artwork: Describe the artwork site and installation method: Describe any required maintenance procedures and/or products: N Attach all that apply: Y Y Y Y N N N Architect’s or Engineer’s preliminary drawings Material samples Images of site or site drawings Manufacturer specs or Material Data Safety Sheets (MSDS) for all commercial products Rev. Jan 2013 Page | 2 Distributed by: Laguna Clay Company 14400 Lomitas Ave City of Industry, CA 91746 1-800-4Laguna info@lagunaclay.com www.lagunaclay.com Ferro Corporation 4150 East 56th Street Cleveland, Ohio 44105 USA Emergency telephone number CHEMTREC: 1-800-424-9300 CHEMTREC (outside U.S.): 1-703-527-3887 Plant Number: 1-216-641-8580 MATERIAL SAFETY DATA SHEET 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Name: Chemical Family: Chemical Name: Synonym CAS-No.: Formula: Product Code: Date of Preparation: 10/25/2011 3134-2 Milled Glaze Frit 50 Lb Bag Frit Frit Glassy mixture of particle size reduction after milling. 65997-18-4 TSCA Description: "Frit is a mixture of inorganic chemical substances produced by rapidly quenching a molten, complex combination of materials, confining the chemical substances thus manufactured as non-migratory components of glassy solid flakes or granules." 1024694 2. HAZARDS IDENTIFICATION Emergency Overview Warning May cause respiratory tract, eye and skin irritation. Do not breathe vapoursldust. Contains crystalline silica which causes silicosis and lung cancer. Color: Physical state: Odor: White Powder Odorless Potential Health Effects Principle routes of exposure: Inhalation, ingestion, skin and eye contact. HMIS 2* o o E NFPA 704 2 o o Eye contact: Skin contact: Inhalation: Ingestion: Chronic toxicity: Contact with eyes may cause irritation. Prolonged skin contact may cause skin irritation. Dust or fumes from firing irritating to respiratory tract. Fumes may cause lung inflammation. May irritate digestive tract. Excessive inhalation of fumes or dust may cause chemical pneumonitis, cyanosis, and pulmonary edema. Respirable crystalline silica has been classified as a Group I (sufficient evidence in humans for carcinogenicity) carcinogenic by IARC and is listed by NTP as a substance which may reasonably be anticipated to be a carcinogen. Long term inhalation causes lung damage (silicosis and cancer). 3. COMPOSITION/INFORMATION ON INGREDIENTS Com onents Frit* Quartz silica CAS Number 14808-60-7 100% Laguna Clay Company www.Lagunaclay.com1-800-4Lagunainfo@Lagunaclay.com Product name: 3134-2 Milled Glaze Frit 50 Lb Bag Page 1 of 5 The specific chemical identities are being withheld as a trade secret (29CFR191 0.1200). * Frit, with CAS # [65997-18-4], is a mixture of inorganic chemical substances produced by rapidly quenching a molten, complex combination of materials, confining the chemical substances thus manufactured as non-migratory components of glassy solid flakes or granules. These components are present as part of the Frit. 4. FIRST AID MEASURES Eye contact: Skin contact: Inhalation: Ingestion: Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if irritation develops. Wash off immediately with soap and plenty of water. Get medical attention if irritation develops. Move to fresh air. If breathing is difficult, give oxygen. If symptoms persist, call a physician. Drink plenty of water. Do not induce vomiting. Consult a physician if necessary. Notes to physician: Treat symptomatically. 5. FIRE-FIGHTING MEASURES Flash point (OC): Non combustible Suitable extinguishing media: The product itself does not burn. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Hazardous decomposition products: Thermal decomposition can lead to release of irritating gases and vapors. Heavy metal compounds. Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus (pressure-demand, NIOSH approved or equivalent) and full protective gear. Unusual hazards: None known. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid dust formation. Do not breathe vapors/dust. Avoid contact with skin, eyes and clothing. Use personal protective equipment. Ensure adequate ventilation. Environmental precautions: Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. Methods for cleaning up: Wear personal protective equipment. Use approved industrial vacuum cleaner for removal. Clean contaminated surface thoroughly. Dispose of promptly. 7. HANDLING AND STORAGE Handling: Handle in accordance with good industrial hygiene and safety practice. Use only in area provided with appropriate exhaust ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin, eyes and clothing. Do not eat, drink, or smoke in areas of use or storage. Storage: Keep in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limits Minimize exposure in accordance with good hygiene practice. Laguna Clay Company www.Lagunaclay.com1-800-4Lagunainfo@Lagunaclay.com Product name: 3134-2 Milled Glaze Frit 50 Lb Bag Page 2 of 5 Comoonents Frit Quartz silica OSHA 0.5 mg/m3 TWA Sb 5 mg/m 3 TWA Zr 5 mq/m3 Ceilinq Mn Listed ACGIH 0.5 mg/m 3 TWA Sb 5 mg/m3 TWA Zr 02 mq/m3 TWA Mn 0.025 mq/m3 TWA respirable fraction Engineering measures: Provide appropriate exhaust ventilation at machinery and at places where dust or fumes can be generated. Ensure that eyewash stations and safety showers are proximal to the work station location. Eye protection: Safety glasses with side-shields. Skin and body protection: Lightweight protective clothing. Keep working clothes separately. Remove and wash contaminated clothing before re-use. Hand protection: Impervious gloves. Respiratory protection: In case of insufficient ventilation wear suitable respiratory equipment. Seek professional advice prior to respirator selection and use. NIOSH-approved respirators should be worn where engineering controls and work practices do not reduce exposure to or below the PEL. Hygiene measures: Wash hands before breaks and at the end of workday. Wash contaminated clothing before re use. 9. PHYSICAL AND CHEMICAL PROPERTIES Color: Odor: Boiling point/range (DC): Melting point/range (DC): Vapor density: Evaporation Rate (Water =1) VOC content (%) White Odorless No data available No data available Non-volatile Non-volatile o Physical state: Molecular weight: pH: Specific gravity (Water =1): Vapor pressure: Water solubility: Powder No data available No data available No data available No data available Insoluble 10. STABILITY AND REACTIVITY Hazardous decomposition products: No decomposition if stored normally. Thermal decomposition can lead to release of irritating Stability: Stable at normal conditions. Polymerization Will not occur. Materials to avoid: Conditions to avoid gases and vapors. None known. None known. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Information given is based on data on the components and the toxicology of similar products. Chronic Toxicity: Contains crystalline silica which causes silicosis and lung cancer. Carcinogenic Effects: Respirable crystalline silica has been classified as a Group I (sufficient evidence in humans for carcinogenicity) carcinogenic by IARC and is listed by NTP as a substance which may reasonably be anticipated to be a carcinogen. Crystalline silica is also a known cause of silicosis, a non-cancerous lung disease caused by excessive exposure to crystalline silica. Target Organ Effects: Silica: Respiratory system. Component information, if any, is listed below Laguna Clay Company www.Lagunaclay.com1-800-4Lagunainfo@Lagunaclay.com Product name: 3134-2 Milled Glaze Frit 50 Lb Bag Page 3 of 5 Frit L050s and LC50s: OSHA - Select Carcinogens: NTP: NTPS. Carcinogen: IARC - Group 1: IARC - Group 2A: IARC - Group 28: Oral LD50 (Rat) = 2000 mg/kg Present Known Human Carcinogen Reasonably Anticipated To Be A Human Carcinogen Listed Listed Listed Quartz silica L050s and LC50s: OSHA - Select Carcinogens: NTP: IARC - Group 1: Oral LD50 (Rat) = 500 mg/kg Present Known Human Carcinogen Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity: No data is available on the product itself. Information given is based on data on the components and the ecotoxicology of similar products. Persistence and degradability: No information available. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Waste must be disposed of in accordance with federal, state and local environmental control regulations. Where possible recycling is preferred to disposal or incineration. DOT (U.S.) Proper shipping name: Not regulated. 14. TRANSPORT INFORMATION TOG (Canada) Proper shipping name: Not regulated. U.S. Regulations: TSCA: 15. REGULATORY INFORMATION Not subject to TSCA 12(b) Export Notification SARA 313: Not subject to the provisions of SARA 313 Title III State Regulations This product or its ingredients have been evaluated for New Jersey, Pennsylvania, and California Prop 65 supplier notification requirements. Substances that are subject to notification requirements, if any, are listed below. Com onents Quartz silica Com onents Quartz silica Canadian WHMIS WHMIS hazard class: D2A Very toxic materials Laguna Clay Company www.Lagunaclay.com1-800-4Lagunainfo@Lagunaclay.com Product name: 3134-2 Milled Glaze Frit 50 Lb Bag Page 4 of 5 International Inventories TSCA 8(b): Canadian DSLlNDSl list EC-No. Philippines (PICCS): Japan (ENCS): Korea (KECl): China (IECS): Australia (AICS): New Zealand (NZloC): Listed or exempt. All ingredient(s) are listed on the DSL or NDSL Listed or exempt. Listed. Listed or exempt. Listed. Listed. Listed. Listed. 16. OTHER INFORMATION For Industrial Use Only. Prepared by: Ferro Technical Center Disclaimer: The information and recommendations contained in this Material Safety Data Sheet have been compiled from sources believed to be reliable and to represent the most reasonable current opinion on the subject when the MSDS was prepared. No warranty, guaranty or representation is made as to the correctness or sufficiency of the information. The user of this product must decide what safety measures are necessary to safely use this product, either alone or in combination with other products, and determine its environmental regulatory compliance obligations under any applicable federal or state laws. End of Safety Data Sheet Distributed by: Laguna Clay Company 14400 Lomitas Ave City of Industry, CA 91746 1-800-4Laguna info@lagunaclay.com www.lagunaclay.com Laguna Clay Company www.Lagunaclay.com1-800-4Lagunainfo@Lagunaclay.com Product name: 3134-2 Milled Glaze Frit 50 Lb Bag Page 5 of 5 SAFETY DATA SHEET * * * Section 1 - Product and Company Identification * * * Chemical Name: Magnesium Silicate Hydrate Product Use: Mineral Additive Synonyms: CIMTUFF® 9100 Series Talc & 9100 W Series Talc, CIMTALC® Series Talc, CLEAR-BLOC ® Talc Series, CLEAR-BLOC 100C® Talc Series, FLEXTALC® Talc Series, ELITETALC® Talc 2000 USP, ELITETALC® Talc 3000 USP, ELITETALC® Talc 4000 USP, ELITETALC® Talc 5000 USP, ELITETALC® Body Powder Talc, NANO-FLEX, RP 9400® Series, Jet Mill Feed, SAS 3. Manufacturer Information (Corporate) CIMBAR Performance Minerals 49-0 Jackson Lake Rd. Chatsworth, Ga. 30705 Phone: 1-800-852-6868 * * * Section 2 - Hazards Identification * * * Signal Word: Warning GHS Classification: Eye, skin, respiratory irritant (Category 4) OSHA\MSHA Hazards: Nuisance Dust Pictogram: Irritant Hazard Statements: Potential Health Effects: Eyes Dust or powder may irritate eye tissue. Potential Health Effects: Skin Dust or powder may irritate the skin. Potential Health Effects: Ingestion May cause temporary irritation of the throat, stomach, and gastrointestinal tract. Emergency Overview: This product is irritating to the eyes, respiratory system and skin. Potential Health Effects: Inhalation Long-term excessive exposures may cause Talcosis, a pulmonary fibrosis, which in turn may lead to severe and permanent damage to the lungs. WARNING: This product contains crystalline silica. Long- term overexposure to crystalline silica causes silicosis, a form of pulmonary fibrosis. Continued overexposure to silica can lead to cardiopulmonary impairment. Crystalline silica has been reviewed by IARC. IARC found sufficient evidence in humans for the carcinogenicity of inhaled crystalline silica in the form of quartz or cristobalite from occupational sources. Medical Conditions Aggravated by Exposure: No information available for the product. Potential Environmental Effects: No significant environmental effects. HMIS Ratings: Health: 1* Fire: 0 Reactivity: 0 Pers. Prot.: E Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard * * * Section 3 - Composition / Information on Ingredients * * * CAS # 14807-96-6 1318-59-8 14808-60-7 Component Talc Chlorite-group minerals Quartz SDS-TALC Revision: 6 (01/01/15) Approval: DBS Percent (wt/wt) 60-100 1-5 0.1-1.0 Page 1 of 6 SAFETY DATA SHEET Component Related Regulatory Information: This product may be regulated, have exposure limits or other information identified as the following: Silica, crystalline (general form). This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication). Component Information: * * * Section 4 - First Aid Measures * * * First Aid: Eyes- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. First Aid: Skin- For skin contact, wash immediately with soap and water. First Aid: Ingestion- Product is not considered toxic in small amounts. First Aid: Inhalation- Move person to non-contaminated air. First Aid: Notes to Physician- Provide general supportive measures and treat symptomatically. * * * Section 5 - Fire Fighting Measures * * * General Fire Hazards: This material will not burn. Hazardous Combustion Products: None identified. Extinguishing Media: Use methods for the surrounding fire. Fire Fighting Equipment/Instructions: None necessary. NFPA Ratings: Health: 1 Fire: 0 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * * * Section 6 - Accidental Release Measures * * * Containment Procedures: Contain the discharged material. Clean-Up Procedures: Provide adequate ventilation. Cleanup personnel should use personal protective equipment to reduce eye contact, inhalation of dust, and prolonged skin contact. Use vacuum equipment with HEPA filters or wet sweeping/dust suppressant if sweeping is required. Personal safety, handling and exposure recommendations described elsewhere in this data sheet apply to exposure during clean up of spilled material and must be followed. Evacuation Procedures: None necessary. Special Procedures: No additional information available. * * * Section 7 - Handling and Storage * * * Handling Procedures: Avoid getting this material into contact with your skin and eyes. Storage Procedures: Store in a cool, dry, well-ventilated area. * * * Section 8 - Exposure Controls / Personal Protection * * * Exposure Guidelines: A: General Product Information Keep formation of airborne dusts to a minimum. SDS-TALC Revision: 6 (01/01/15) Approval: DBS Page 2 of 6 SAFETY DATA SHEET B: Component Exposure Limits Talc (14807-96-6) silica) Quartz (14808-60-7) ACGIH: 2 mg/m3 TWA (respirable fraction, particulate matter containing no asbestos and <1% crystalline OSHA: 2 mg/m3 TWA (respirable dust, less than 1% crystalline silica) NIOSH: 2 mg/m3 TWA (respirable dust, containing no asbestos and less than 1% quartz) ACGIH: 0.025 mg/m3 TWA (respirable fraction) OSHA: 0.1 mg/m3 TWA (respirable dust) NIOSH: 0.05 mg/m3 TWA (respirable dust) limits. Engineering Controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure Personal Protective Equipment (PPE): Eyes/Face- Wear dust goggles. Skin- Use impervious gloves. Respiratory- Use a dust mask for particulate concentrations exceeding the Occupational Exposure Limit. General- Eye wash fountain and emergency showers are recommended. * * * Section 9 - Physical & Chemical Properties * * * Appearance: White Powder Physical State: Solid Vapor Pressure: N/A Boiling Point: N/A Solubility (H2O): Insoluble Odor: None pH: N/A Vapor Density: N/A Melting Point: Unknown Specific Gravity: 2.8 * * * Section 10 - Stability & Reactivity * * * Chemical Stability: Stable under normal conditions. Chemical Stability: Conditions to Avoid- None. Incompatibility: None identified. Hazardous Decomposition: None identified. Hazardous Polymerization: Will not occur. Acute and Chronic Toxicity: * * * Section 11 - Toxicological Information * * * A: General Product Information- No information available for the product. B: Component Analysis - LD50/LC50 Quartz (14808-60-7) SDS-TALC Revision: 6 (01/01/15) Approval: DBS Page 3 of 6 SAFETY DATA SHEET Oral LD50 Rat: 500 mg/kg Carcinogenicity: A: General Product Information- Not listed by ACGIH, IARC, NIOSH, NTP OR OSHA. B: Component Carcinogenicity Talc (14807-96-6) ACGIH: A4 - Not Classifiable as a Human Carcinogen (containing no asbestos fibers); A1 - Confirmed Human Carcinogen (containing asbestos fibers) IARC: Monograph 93 [in preparation] (inhaled), Supplement 7 [1987], Monograph 42 [1987] (Group 3 (not classifiable)) Quartz (14808-60-7) ACGIH: A2 - Suspected Human Carcinogen NIOSH: potential occupational carcinogen NTP: Known Human Carcinogen (Select Carcinogen) IARC: Monograph 68 [1997] (listed under Crystalline silica inhaled in the form of quartz or cristobalite from occupational sources) (Group 1 (carcinogenic to humans)) * * * Section 12 - Ecological Information * * * A: General Product Information- This material is not expected to be harmful to aquatic life. B: Component Analysis - Ecotoxicity - Aquatic Toxicity Talc (14807-96-6) 96 Hr LC50 Brachydanio rerio: >100 g/L [semi-static] Ecotoxicity: Environmental Fate- This material shows no bioaccumulation or food chain concentration toxicity potential. * * * Section 13 - Disposal Considerations * * * US EPA Waste Number & Descriptions: Disposal Instructions: A: General Product Information- No components are identified as hazardous wastes. B: Component Waste Numbers- No EPA Waste Numbers are applicable for this product's components. If this material becomes a waste it does not meet the criteria of a hazardous waste as defined by USEPA RCRA regulations. More stringent state or local regulations may apply. Combining this material with another may alter this classification. * * * Section 14 - Transport Information * * * US DOT Information: Not regulated. International Transportation Regulations: This product is not regulated as a hazardous material by the United States (DOT) or Canadian (TDG) transportation regulations. * * * Section 15 - Regulatory Information * * * US Federal Regulations: A: General Product Information TSCA - All naturally occurring components of this product are automatically included in the USEPA TSCA Inventory List per 40 CFR 710.4 (b). All other components are on the USEPA TSCA Inventory List. SDS-TALC Revision: 6 (01/01/15) Approval: DBS Page 4 of 6 SAFETY DATA SHEET FDA - 1. Generally acceptable for use in vanilla powder and vanilla-vanillan powder under food standards 21 CFR 169.179 and 169.182. 2. Generally Recognized As Safe as an anticaking agent in table salt up to 2% (21 CFR 182.2437). 3. Generally approved for use as a pigment or colorant under 21 CFR 175.300, 175.380, 175.390, 176.170, 177.1210, 177.1350, and 177.1460. 4. Generally approved for use as a colorant in polymers (21 CFR 178.3297). Generally approved for use as a colorant only as components of paper and paperboard in contact with aqueous fatty foods (21 CFR 176.170). B: Component Analysis: None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), or CERCLA (40 CFR 302.4). Acute Health: Yes Chronic Health: Yes Fire: No Pressure: No Reactive: No State Regulations: A: General Product Information Other state regulations may apply. Check individual state requirements. B: Component Analysis - State The following components appear on one or more of the following state hazardous substances lists: Component Talc Quartz CAS 14807-96-6 14808-60-7 CA Yes No FL No No MA Yes Yes MN Yes Yes NJ Yes Yes PA Yes Yes MI No No The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): WARNING! This product contains a chemical known to the state of California to cause cancer. A: General Product Information Canadian WHMIS Classification: Class D, Division 2, Subdivision A B: Component Analysis - Inventory CAS # Component Country EINECS Europe DSL Canada PICCS PHIL. TSCA USA AICS Aust. 14807-96-6 1318-59-8 Talc Chlorite-group minerals Quartz No*- There exists a broad category for naturally occurring chemicals, so these minerals are covered by definition, but not specifically listed. 14808-60-7 Yes No* Yes No* Yes Yes Yes Yes Yes No* Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes ENCS Japan KECI Korea IECSC China NZIoC New Zealand Yes Yes Other Regulations: C: Component Analysis - WHMIS IDL Component Quartz 15.1 Chemical Safety Assessment- REACH: Exempted from REACH registration in accordance with Annex V.7 CAS 14808-60-7 Present Yes SDS-TALC Revision: 6 (01/01/15) Approval: DBS Page 5 of 6 SAFETY DATA SHEET * * * Section 16 - Other Information * * * Other Information: Disclaimer: CIMBAR Performance Minerals (CPM) is not responsible for the use of information, product, method, or apparatus herein presented ("Information"), and you must make your own determination as to its suitability and completeness for your own use, for the protection of the environment, and for health and safety purposes. You assume the entire risk of relying on this information. In no event shall CPM be responsible for damages of any nature whatsoever resulting from the use of or reliance upon this information. By providing this information, CPM neither can nor intends to control the method or manner by which you use, handle, store, or transport CPM products. Nothing herein shall be construed as a recommendation or license to use any Information that conflicts with any patent, trademark or copyright. Safety Data Sheets providing safety precautions that should be observed in handling and storing CPM products are available upon request. You should obtain and review the available material safety information before handling any of these products. CPM MAKES NO PRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE REGARDING THIS INFORMATION, AND NOTHING HEREIN WAIVES ANY CONDITIONS OF SALE. This information could include technical inaccuracies or typographical errors. Changes are periodically added to the information herein; these changes will be incorporated in revisions of the information. CPM may make improvements and/or changes in the product(s) described in this information at any given time. EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration; DOT = Department of Transportation; RCRA = Resource Conservation and Recovery Act Key/Legend: SDS-TALC Revision: 6 (01/01/15) Approval: DBS Page 6 of 6 -Standard Clay, Sculpture body #420 (30 % grog content ﬁred to cone 6) List of Materials Ceramic Tiles and Glazes EPK Kaolin (Edgar Clay) Custom mixed glazes - Custer Feldspar Spodumene - Silica - Talc - - EPK - Ball Clay 0M4 Frit 3134 - - Frit 3195 - Wollastonite Mason Stains - Chrome �n pink sphene – Alpine Rose - Chrome �n pink sphene – Crimson - Cobalt Silicate Blue Olivine – Mazurine and Pansy Purple - Cobalt Zinc Aluminate Blue Spinel – Vivid Blue - Cobalt Tin Alumina Blue Spinel – Delphinium Blue Installa�on Thin Tile mortar Laticrete Multimax Lite - Strong exterior, large and heavy tile mortar - 600 PSI shear strength Spectalock Pro Premium Grout - Epoxy based grout Sealant World’s best an�-graﬃ� sealant Safety Data Sheet DATE PREPARED 4/28/2015 6001 CHROME TIN PINK SPHENE HMIS Classification: Health Flammability Reactivity Personal Protection 1.1 Product identifier 2* 0 0 See Section 8 Product name CHROME TIN PINK SPHENE Chrome Tin Pink Sphene, an inorganic pigment, is a reaction product of high temperature calcination in which Calcium (II) Oxide, Tin (IV) Oxide, Silicon (IV) Oxide, and Chromium (III) Oxide in varying amounts are homogeneously and ionically interdiffused to form a crystalline matrix of tin sphene. Its composition may include either or both of the modifiers B2O3 and PbO Product number EC no. CAS no. Index no. 1.4 Supplier’s details Name Address Telephone Fax 6001 ALPINE ROSE 269-073-6 68187-12-2 C.I. 77301 Mason Color Works Inc. 250 East Second Street East Livepool, Ohio 43920 USA 330 385 4400 330 385 4488 SECTION 2: Hazard identification 2.1 Classification of the substance or mixture GHS classification in accordance with OSHA (29 CFR 1910.1200) Not a hazardous substance or mixture. 2.2 GHS label elements, including precautionary statements Not a hazardous substance or mixture. 2.3 Other hazards which do not result in classification Not a hazardous substance or mixture. SECTION 3: Composition/information on ingredients 6001 CHROME TIN PINK SPHENE C.I. Pigment Red 233 100% EC no. CAS no. Index no. Formula 269-073-6 68187-12-2 C.I. 77301 CaO:SnO:SiO2:Cr2O3 SECTION 4: First-aid measures •Contact with skin: •Contact with eyes: •Swallowing: Wash with plenty of water and soap. Wash immediately with water for at least 10 minutes. Induce vomiting. SEEK A MEDICAL EXAMINATION IMMEDIATELY and present the safety-data sheet. A suspension of activated charcoal in water, or liquid paraffin may be administered. •Inhalation: Ventilate the premises. The patient is to be removed immediately from the contaminated premises and made to rest in a well ventilated area. Should the patient feel unwell, OBTAIN MEDICAL ATTENTION SECTION 5: Fire-fighting measures •Recommended extinguishers: •Extinguishers not to be used: •Risks arising from combustion: •Protective equipment: SECTION 6: Accidental release measures Water, CO2, Foam, Chemical powders, according to the materials involved in the fire. None in particular. Avoid inhaling the fumes. Use protection for the respiratory tract. •Measures for personal safety: •Environmental measures: . •Cleaning methods: Use gloves and protective clothing. In the event of particulates aerosols use respiratory protection. Keep away from drains, surface- and ground-water and soil Limit leakages with earth or sand. If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities. Remove the waste materials with a suitable device (for instance a suction pump) and dispose. After the product has been recovered, rinse the area and materials involved with water. SECTION 7: Handling and storage •Handling precautions: Wear suitable gloves, glasses and face protection. Avoid contact and inhalation of the vapours/powders. •Incompatible materials: •Storage conditions: •Instructions as regards storage premises: Do not eat or drink while working. None in particular. Always keep the containers tightly closed. Adequately ventilated premises. SECTION 8: Exposure controls / personal protection Tin Oxide (as Sn) (Total Dust) Chromium (III) Compounds (as Cr) Silica, Crystalline (SiO2) ACGIH-TLVs 2.0 mg/m3 0.5 mg/m3 0.1 mg/m3 OSHA PELs 2.0 mg/m3 0.5 mg/m3 10 mg/m3 NOISHA RELs 2.0 mg/m3 0.5 mg/m3 0.05 mg/m3 •Precautionary measures: •Respiratory protection: •Protection for hands: •Eye protection: •Protection for skin: Give adequate ventilation to the premises where the product is stored and/or handled. Use suitable respiratory protection. Not needed for normal use. Not needed for normal use. No special precaution must be adopted for normal use. SECTION 9: Physical and chemical properties Appearance/form PINK/POWDER Odor pH SPECIFIC GRAVITY Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability limits Upper/lower explosive limits Vapor pressure Vapor density Relative density Solubility(ies) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties None 3.84 6.6 >1000c none NA NA NA NA NA NA NA NA NA NA NA NA none none insoluble SECTION 10: Stability and reactivity Chemical stability STABLE Possibility of hazardous reactions WILL NOT OCCUR Incompatible materials Hazardous decomposition products NONE N/A SECTION 11: Toxicological information ORAL SKIN INHALATION NON IRRITATING TO THE SKIN NON IRRITATING TO THE EYES LD50 (male and female rats) > 2200 mg/kg LC50 (male and female rats; 4 hours) > 5.4 mg/L UNKNOWN THIS PIGMENT IS NOT LISTED IN THE NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS. IT IS NOT LISTED AS A POTENTIAL CARCINOGEN IN THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER(IARC) MONOGRAPHS. IT IS NOT FOUND TO BE A CARCINOGEN BY THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION(OSHA) SECTION 12: Ecological information ECOTOXICITY DEGRADABILITY MOBILITY BIOACCUMULATIVE NO DATA NO DATA NO DATA NO DATA SECTION 13: Disposal considerations Disposal of the product Contain spillage and scoop or vacuum. Avoid making dust put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. Disposal of contaminated packaging Dispose of as unused product. Waste treatment Sewage disposal MUST BE PROCESSED THROUGH IN-HOUSE TREATMENT AVOID CITY DRAINS SECTION 14: Transport information 14.1 UN Number 14.2 UN Proper Shipping Name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code None None None None None None None SECTION 15: Regulatory information Attention all Retailers of Mason Stains ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 using this material. OR BY REQUEST. Disclamer This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this SDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! SDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT SECTION 16: REFERENCE INFORMATION CPMA CLASSIFICATION AND CHEMICAL DESCRIPTIONS OF THE COMPLEX INORGANIC COLOR PIGMENTS Fourth Edition - January 2013 Update https://www.osha.gov/index.html http://chem.sis.nlm.nih.gov/chemidplus 13th Report on Carcinogens on October 2, 2014. http://monographs.iarc.fr/ENG/Classification/index.php Safety Data Sheet DATE PREPARED 4/28/2015 6003 CHROME TIN PINK SPHENE HMIS Classification: Health Flammability Reactivity Personal Protection 1.1 Product identifier 2* 0 0 See Section 8 Product name CHROME TIN PINK SPHENE Chrome Tin Pink Sphene, an inorganic pigment, is a reaction product of high temperature calcination in which Calcium (II) Oxide, Tin (IV) Oxide, Silicon (IV) Oxide, and Chromium (III) Oxide in varying amounts are homogeneously and ionically interdiffused to form a crystalline matrix of tin sphene. Its composition may include either or both of the modifiers B2O3 and PbO Product number EC no. CAS no. Index no. 1.4 Supplier’s details Name Address Telephone Fax 6003 CRIMSON 269-073-6 68187-12-2 C.I. 77301 Mason Color Works Inc. 250 East Second Street East Livepool, Ohio 43920 USA 330 385 4400 330 385 4488 SECTION 2: Hazard identification 2.1 Classification of the substance or mixture GHS classification in accordance with OSHA (29 CFR 1910.1200) Not a hazardous substance or mixture. 2.2 GHS label elements, including precautionary statements Not a hazardous substance or mixture. 2.3 Other hazards which do not result in classification Not a hazardous substance or mixture. SECTION 3: Composition/information on ingredients 6003 CHROME TIN PINK SPHENE C.I. Pigment Red 233 100% EC no. CAS no. Index no. Formula 269-073-6 68187-12-2 C.I. 77301 CaO:SnO:SiO2:Cr2O3 SECTION 4: First-aid measures •Contact with skin: •Contact with eyes: •Swallowing: Wash with plenty of water and soap. Wash immediately with water for at least 10 minutes. Induce vomiting. SEEK A MEDICAL EXAMINATION IMMEDIATELY and present the safety-data sheet. A suspension of activated charcoal in water, or liquid paraffin may be administered. •Inhalation: Ventilate the premises. The patient is to be removed immediately from the contaminated premises and made to rest in a well ventilated area. Should the patient feel unwell, OBTAIN MEDICAL ATTENTION SECTION 5: Fire-fighting measures •Recommended extinguishers: •Extinguishers not to be used: •Risks arising from combustion: •Protective equipment: SECTION 6: Accidental release measures Water, CO2, Foam, Chemical powders, according to the materials involved in the fire. None in particular. Avoid inhaling the fumes. Use protection for the respiratory tract. •Measures for personal safety: •Environmental measures: . •Cleaning methods: Use gloves and protective clothing. In the event of particulates aerosols use respiratory protection. Keep away from drains, surface- and ground-water and soil Limit leakages with earth or sand. If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities. Remove the waste materials with a suitable device (for instance a suction pump) and dispose. After the product has been recovered, rinse the area and materials involved with water. SECTION 7: Handling and storage •Handling precautions: Wear suitable gloves, glasses and face protection. Avoid contact and inhalation of the vapours/powders. •Incompatible materials: •Storage conditions: •Instructions as regards storage premises: Do not eat or drink while working. None in particular. Always keep the containers tightly closed. Adequately ventilated premises. SECTION 8: Exposure controls / personal protection Tin Oxide (as Sn) (Total Dust) Chromium (III) Compounds (as Cr) Silica, Crystalline (SiO2) ACGIH-TLVs 2.0 mg/m3 0.5 mg/m3 0.1 mg/m3 OSHA PELs 2.0 mg/m3 0.5 mg/m3 10 mg/m3 NOISHA RELs 2.0 mg/m3 0.5 mg/m3 0.05 mg/m3 •Precautionary measures: •Respiratory protection: •Protection for hands: •Eye protection: •Protection for skin: Give adequate ventilation to the premises where the product is stored and/or handled. Use suitable respiratory protection. Not needed for normal use. Not needed for normal use. No special precaution must be adopted for normal use. SECTION 9: Physical and chemical properties Appearance/form PINK/POWDER Odor pH SPECIFIC GRAVITY Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability limits Upper/lower explosive limits Vapor pressure Vapor density Relative density Solubility(ies) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties None 3.84 6.6 >1000c none NA NA NA NA NA NA NA NA NA NA NA NA none none insoluble SECTION 10: Stability and reactivity Chemical stability STABLE Possibility of hazardous reactions WILL NOT OCCUR Incompatible materials Hazardous decomposition products NONE N/A SECTION 11: Toxicological information ORAL SKIN INHALATION NON IRRITATING TO THE SKIN NON IRRITATING TO THE EYES LD50 (male and female rats) > 2200 mg/kg LC50 (male and female rats; 4 hours) > 5.4 mg/L UNKNOWN THIS PIGMENT IS NOT LISTED IN THE NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS. IT IS NOT LISTED AS A POTENTIAL CARCINOGEN IN THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER(IARC) MONOGRAPHS. IT IS NOT FOUND TO BE A CARCINOGEN BY THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION(OSHA) SECTION 12: Ecological information ECOTOXICITY DEGRADABILITY MOBILITY BIOACCUMULATIVE NO DATA NO DATA NO DATA NO DATA SECTION 13: Disposal considerations Disposal of the product Contain spillage and scoop or vacuum. Avoid making dust put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. Disposal of contaminated packaging Dispose of as unused product. Waste treatment Sewage disposal MUST BE PROCESSED THROUGH IN-HOUSE TREATMENT AVOID CITY DRAINS SECTION 14: Transport information 14.1 UN Number 14.2 UN Proper Shipping Name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code None None None None None None None SECTION 15: Regulatory information Attention all Retailers of Mason Stains ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 using this material. OR BY REQUEST. Disclamer This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this SDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! SDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT SECTION 16: REFERENCE INFORMATION CPMA CLASSIFICATION AND CHEMICAL DESCRIPTIONS OF THE COMPLEX INORGANIC COLOR PIGMENTS Fourth Edition - January 2013 Update https://www.osha.gov/index.html http://chem.sis.nlm.nih.gov/chemidplus 13th Report on Carcinogens on October 2, 2014. http://monographs.iarc.fr/ENG/Classification/index.php Safety Data Sheet DATE PREPARED 4/28/2015 6006 CHROME TIN PINK SPHENE HMIS Classification: Health Flammability Reactivity Personal Protection 1.1 Product identifier 2* 0 0 See Section 8 Product name CHROME TIN PINK SPHENE Chrome Tin Pink Sphene, an inorganic pigment, is a reaction product of high temperature calcination in which Calcium (II) Oxide, Tin (IV) Oxide, Silicon (IV) Oxide, and Chromium (III) Oxide in varying amounts are homogeneously and ionically interdiffused to form a crystalline matrix of tin sphene. Its composition may include either or both of the modifiers B2O3 and PbO Product number EC no. CAS no. Index no. 1.4 Supplier’s details Name Address Telephone Fax 6006 DEEP CRIMSON 269-073-6 68187-12-2 C.I. 77301 Mason Color Works Inc. 250 East Second Street East Livepool, Ohio 43920 USA 330 385 4400 330 385 4488 SECTION 2: Hazard identification 2.1 Classification of the substance or mixture GHS classification in accordance with OSHA (29 CFR 1910.1200) Not a hazardous substance or mixture. 2.2 GHS label elements, including precautionary statements Not a hazardous substance or mixture. 2.3 Other hazards which do not result in classification Not a hazardous substance or mixture. SECTION 3: Composition/information on ingredients 6006 CHROME TIN PINK SPHENE C.I. Pigment Red 233 100% EC no. CAS no. Index no. Formula 269-073-6 68187-12-2 C.I. 77301 CaO:SnO:SiO2:Cr2O3 SECTION 4: First-aid measures •Contact with skin: •Contact with eyes: •Swallowing: Wash with plenty of water and soap. Wash immediately with water for at least 10 minutes. Induce vomiting. SEEK A MEDICAL EXAMINATION IMMEDIATELY and present the safety-data sheet. A suspension of activated charcoal in water, or liquid paraffin may be administered. •Inhalation: Ventilate the premises. The patient is to be removed immediately from the contaminated premises and made to rest in a well ventilated area. Should the patient feel unwell, OBTAIN MEDICAL ATTENTION SECTION 5: Fire-fighting measures •Recommended extinguishers: •Extinguishers not to be used: •Risks arising from combustion: •Protective equipment: SECTION 6: Accidental release measures Water, CO2, Foam, Chemical powders, according to the materials involved in the fire. None in particular. Avoid inhaling the fumes. Use protection for the respiratory tract. •Measures for personal safety: •Environmental measures: . •Cleaning methods: Use gloves and protective clothing. In the event of particulates aerosols use respiratory protection. Keep away from drains, surface- and ground-water and soil Limit leakages with earth or sand. If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities. Remove the waste materials with a suitable device (for instance a suction pump) and dispose. After the product has been recovered, rinse the area and materials involved with water. SECTION 7: Handling and storage •Handling precautions: Wear suitable gloves, glasses and face protection. Avoid contact and inhalation of the vapours/powders. •Incompatible materials: •Storage conditions: •Instructions as regards storage premises: Do not eat or drink while working. None in particular. Always keep the containers tightly closed. Adequately ventilated premises. SECTION 8: Exposure controls / personal protection Tin Oxide (as Sn) (Total Dust) Chromium (III) Compounds (as Cr) Silica, Crystalline (SiO2) ACGIH-TLVs 2.0 mg/m3 0.5 mg/m3 0.1 mg/m3 OSHA PELs 2.0 mg/m3 0.5 mg/m3 10 mg/m3 NOISHA RELs 2.0 mg/m3 0.5 mg/m3 0.05 mg/m3 •Precautionary measures: •Respiratory protection: •Protection for hands: •Eye protection: •Protection for skin: Give adequate ventilation to the premises where the product is stored and/or handled. Use suitable respiratory protection. Not needed for normal use. Not needed for normal use. No special precaution must be adopted for normal use. SECTION 9: Physical and chemical properties Appearance/form PINK/POWDER Odor pH SPECIFIC GRAVITY Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability limits Upper/lower explosive limits Vapor pressure Vapor density Relative density Solubility(ies) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties None 3.84 6.6 >1000c none NA NA NA NA NA NA NA NA NA NA NA NA none none insoluble SECTION 10: Stability and reactivity Chemical stability STABLE Possibility of hazardous reactions WILL NOT OCCUR Incompatible materials Hazardous decomposition products NONE N/A SECTION 11: Toxicological information ORAL SKIN INHALATION NON IRRITATING TO THE SKIN NON IRRITATING TO THE EYES LD50 (male and female rats) > 2200 mg/kg LC50 (male and female rats; 4 hours) > 5.4 mg/L UNKNOWN THIS PIGMENT IS NOT LISTED IN THE NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS. IT IS NOT LISTED AS A POTENTIAL CARCINOGEN IN THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER(IARC) MONOGRAPHS. IT IS NOT FOUND TO BE A CARCINOGEN BY THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION(OSHA) SECTION 12: Ecological information ECOTOXICITY DEGRADABILITY MOBILITY BIOACCUMULATIVE NO DATA NO DATA NO DATA NO DATA SECTION 13: Disposal considerations Disposal of the product Contain spillage and scoop or vacuum. Avoid making dust put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. Disposal of contaminated packaging Dispose of as unused product. Waste treatment Sewage disposal MUST BE PROCESSED THROUGH IN-HOUSE TREATMENT AVOID CITY DRAINS SECTION 14: Transport information 14.1 UN Number 14.2 UN Proper Shipping Name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code None None None None None None None SECTION 15: Regulatory information Attention all Retailers of Mason Stains ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 using this material. OR BY REQUEST. Disclamer This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this SDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! SDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT SECTION 16: REFERENCE INFORMATION CPMA CLASSIFICATION AND CHEMICAL DESCRIPTIONS OF THE COMPLEX INORGANIC COLOR PIGMENTS Fourth Edition - January 2013 Update https://www.osha.gov/index.html http://chem.sis.nlm.nih.gov/chemidplus 13th Report on Carcinogens on October 2, 2014. http://monographs.iarc.fr/ENG/Classification/index.php Safety Data Sheet DATE PREPARED 4/28/2015 UPDATED 3/21/2016 6306 COBALT ZINC ALUMINATE BLUE SPINEL HMIS Classification: Health Flammability Reactivity 2* 0 0 Personal Protection See Section 8 1.1 Product identifier Product name COBALT ZINC ALUMINATE BLUE SPINEL Cobalt Zinc Aluminate Blue Spinel, an inorganic pigment, is a reaction product of high temperature calcination in which Cobalt (II) Oxide, Zinc (II) Oxide, and Aluminum (III) Oxide in varying amounts are homogeneously and ionically interdiffused to form a crystalline matrix of spinel. Its composition may include any one or a combination of the modifiers Li2O, MgO, SiO2, SnO or TiO2 Product number EC no. CAS no. Index no. 1.4 Supplier’s details Name Address Telephone Fax 6306 VIVID BLUE 269-049-5 68186-87-8 C.I. 77347 Mason Color Works Inc. 250 East Second Street East Livepool, Ohio 43920 USA 330 385 4400 330 385 4488 SECTION 2: Hazard Identification Signal Word: WARNING Not a hazardous substance GHS classification in accordance with OSHA (29 CFR 1910.1200) P261: Avoid breathing dust. H303: May be harmful if swallowed P262: Do not get in eyes, on skin. H313: May be harmful in contact with skin P264: Wash hands thoroughly after handling. H317: May cause an allergic skin reaction H333: May be harmful if inhaled H335: May cause respiratory irritation SECTION 3: Composition/information on ingredients COBALT ZINC ALUMINATE BLUE SPINEL C.I. Pigment Blue 72 100% EC no. CAS no. Index no. Formula 269-049-5 68186-87-8 C.I. 77347 (Co,Zn)Al2O4 SECTION 4: First-aid measures •Contact with skin: •Contact with eyes: •Swallowing: Wash with plenty of water and soap. Wash immediately with water for at least 10 minutes. Induce vomiting. SEEK A MEDICAL EXAMINATION IMMEDIATELY and present the safety-data sheet. A suspension of activated charcoal in water, or liquid paraffin may be administered. •Inhalation: Ventilate the premises. The patient is to be removed immediately from the contaminated premises and made to rest in a well ventilated area. Should the patient feel unwell, OBTAIN MEDICAL ATTENTION SECTION 5: Fire-fighting measures •Recommended extinguishers: •Extinguishers not to be used: •Risks arising from combustion: •Protective equipment: SECTION 6: Accidental release measures Water, CO2, Foam, Chemical powders, according to the materials involved in the fire. None in particular. Avoid inhaling the fumes. Use protection for the respiratory tract. •Measures for personal safety: •Environmental measures: . •Cleaning methods: Use gloves and protective clothing. In the event of particulates aerosols use respiratory protection. Keep away from drains, surface- and ground-water and soil Limit leakages with earth or sand. If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities. Remove the waste materials with a suitable device (for instance a suction pump) and dispose. After the product has been recovered, rinse the area and materials involved with water. •Handling precautions: Wear suitable gloves, glasses and face protection. Avoid contact and inhalation of the vapours/powders. SECTION 7: Handling and storage •Incompatible materials: •Storage conditions: •Instructions as regards storage premises: Do not eat or drink while working. None in particular. Always keep the containers tightly closed. Adequately ventilated premises. SECTION 8: Exposure controls / personal protection Cobalt, Metal, Dust & Fume (as Co) Aluminum (as Al), Metal (Total Dust) Zinc oxide(as Zn) (Total Dust) ACGIH-TLVs 0.02 mg/m3 10 mg/mg3 (total) 10 mg/m3 OSHA PELs 0.5 mg/m3 15 mg/m3 (total) 10 mg/m3(total) 5 mg/m3 (respirable) NOISHA RELs N/A N/A 5 mg/m3 Give adequate ventilation to the premises where the product is stored and/or handled. •Precautionary measures: •Respiratory protection: •Protection for hands: •Eye protection: •Protection for skin: SECTION 9: Physical and chemical properties Appearance/form Blue/Powder Use suitable respiratory protection. Not needed for normal use. Not needed for normal use. No special precaution must be adopted for normal use. Odor pH SPECIFIC GRAVITY Flash point Evaporation rate Melting point/freezing point Initial boiling point and boiling range Flammability (solid, gas) none Upper/lower flammability limits Upper/lower explosive limits Vapor pressure Vapor density Relative density Solubility(ies) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties None 4.49 6.6 <1000 C NA NA NA NA NA NA NA NA NA NA NA NA none none insoluble SECTION 10: Stability and reactivity Chemical stability STABLE Possibility of hazardous reactions WILL NOT OCCUR Incompatible materials Hazardous decomposition products NONE N/A SECTION 11: Toxicological information INHALATION ORAL SKIN NON IRRITATING TO THE SKIN NON IRRITATING TO THE EYES LD50 (male rats) > 10000 mg/kg LC50 (rats; 4 hours) > >5.06 mg/L air N/A THIS PIGMENT IS NOT LISTED IN THE NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS. IT IS NOT LISTED AS A POTENTIAL CARCINOGEN IN THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER(IARC) MONOGRAPHS. IT IS NOT FOUND TO BE A CARCINOGEN BY THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION(OSHA) SECTION 12: Ecological information ECOTOXICITY DEGRADABILITY MOBILITY BIOACCUMULATIVE NO DATA NO DATA NO DATA NO DATA SECTION 13: Disposal considerations Disposal of the product Contain spillage and scoop or vacuum. Avoid making dust put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. Disposal of contaminated packaging Dispose of as unused product. Waste treatment MUST BE PROCESSED THROUGH IN-HOUSE TREATMENT Sewage disposal AVOID CITY DRAINS SECTION 14: Transport information 14.1 UN Number 14.2 UN Proper Shipping Name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code None None None None None None None SECTION 15: Regulatory information Attention all Retailers of Mason Stains ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 using this material. OR BY REQUEST. Disclamer This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT SECTION 16: REFERENCE INFORMATION CPMA CLASSIFICATION AND CHEMICAL DESCRIPTIONS OF THE COMPLEX INORGANIC COLOR PIGMENTS Fourth Edition - January 2013 Update https://www.osha.gov/index.html http://chem.sis.nlm.nih.gov/chemidplus 13th Report on Carcinogens on October 2, 2014. http://monographs.iarc.fr/ENG/Classification/index.php Safety Data Sheet DATE PREPARED 4/28/2015 UPDATED 3/21/2016 6308 COBALT TIN ALUMINA BLUE SPINEL HMIS Classification: Health Flammability Reactivity 2* 0 0 Personal Protection See Section 8 1.1 Product identifier Product name COBALT TIN ALUMINA BLUE SPINEL Cobalt Tin Alumina Blue Spinel, an inorganic pigment, is the reaction product of high temperature calcination in which Aluminum (III) Oxide, Cobalt (II) Oxide, and Tin (IV) Oxide in varying amounts are homogeneously and ionically interdiffused to form a crystalline matrix of spinel. Its composition may include either one or both of the modifiers SiO2, or ZnO Product number EC no. CAS no. Index no. 1.4 Supplier’s details Name Address Telephone Fax 6308 DELPHINIUM BLUE 271-771-0 68186-95-8 C.I. 77998 Mason Color Works Inc. 250 East Second Street East Livepool, Ohio 43920 USA 330 385 4400 330 385 4488 SECTION 2: Hazard Identification Signal Word: WARNING Not a hazardous substance GHS classification in accordance with OSHA (29 CFR 1910.1200) P261: Avoid breathing dust. H303: May be harmful if swallowed P262: Do not get in eyes, on skin. H313: May be harmful in contact with skin P264: Wash hands thoroughly after handling. H317: May cause an allergic skin reaction H333: May be harmful if inhaled H335: May cause respiratory irritation SECTION 3: Composition/information on ingredients COBALT TIN ALUMINA BLUE SPINEL C.I. Pigment Blue 81 100% EC no. CAS no. Index no. Formula 271-771-0 68186-95-8 C.I. 77998 CoA12O4/Co2SnO4 SECTION 4: First-aid measures •Contact with skin: •Contact with eyes: •Swallowing: Wash with plenty of water and soap. Wash immediately with water for at least 10 minutes. Induce vomiting. SEEK A MEDICAL EXAMINATION IMMEDIATELY and present the safety-data sheet. A suspension of activated charcoal in water, or liquid paraffin may be administered. •Inhalation: Ventilate the premises. The patient is to be removed immediately from the contaminated premises and made to rest in a well ventilated area. Should the patient feel unwell, OBTAIN MEDICAL ATTENTION SECTION 5: Fire-fighting measures •Recommended extinguishers: •Extinguishers not to be used: •Risks arising from combustion: •Protective equipment: SECTION 6: Accidental release measures Water, CO2, Foam, Chemical powders, according to the materials involved in the fire. None in particular. Avoid inhaling the fumes. Use protection for the respiratory tract. •Measures for personal safety: •Environmental measures: . •Cleaning methods: Use gloves and protective clothing. In the event of particulates aerosols use respiratory protection. Keep away from drains, surface- and ground-water and soil Limit leakages with earth or sand. If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities. Remove the waste materials with a suitable device (for instance a suction pump) and dispose. After the product has been recovered, rinse the area and materials involved with water. SECTION 7: Handling and storage •Handling precautions: Wear suitable gloves, glasses and face protection. Avoid contact and inhalation of the vapours/powders. •Incompatible materials: •Storage conditions: •Instructions as regards storage premises: Do not eat or drink while working. None in particular. Always keep the containers tightly closed. Adequately ventilated premises. SECTION 8: Exposure controls / personal protection Cobalt, Metal, Dust & Fume (as Co) Aluminum (as Al), Metal (Total Dust) Tin Oxide (as Sn) (Total Dust) ACGIH-TLVs 0.02 mg/m3 10 mg/mg3 (total) 2.0 mg/m3 OSHA PELs 0.5 mg/m3 15 mg/m3 (total) 2.0 mg/m3 NOISHA RELs N/A N/A 2.0 mg/m3 •Precautionary measures: •Respiratory protection: •Protection for hands: •Eye protection: •Protection for skin: Give adequate ventilation to the premises where the product is stored and/or handled. Use suitable respiratory protection. Not needed for normal use. Not needed for normal use. No special precaution must be adopted for normal use. SECTION 9: Physical and chemical properties Appearance/form Blue/Powder Odor pH SPECIFIC GRAVITY Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability limits Upper/lower explosive limits Vapor pressure Vapor density Relative density Solubility(ies) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties None 4.26 6.6 >1000c none NA NA NA NA NA NA NA NA NA NA NA NA none none insoluble SECTION 10: Stability and reactivity Chemical stability STABLE Possibility of hazardous reactions WILL NOT OCCUR Incompatible materials NONE Hazardous decomposition products N/A SECTION 11: Toxicological information ORAL SKIN INHALATION NON IRRITATING TO THE SKIN NON IRRITATING TO THE EYES LD50 (male rats) > 10000 mg/kg LC50 (rats; 4 hours) > >5.06 mg/L air N/A THIS PIGMENT IS NOT LISTED IN THE NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS. IT IS NOT LISTED AS A POTENTIAL CARCINOGEN IN THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER(IARC) MONOGRAPHS. IT IS NOT FOUND TO BE A CARCINOGEN BY THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION(OSHA) Disposal of the product Contain spillage and scoop or vacuum. Avoid making dust put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. Disposal of contaminated packaging Dispose of as unused product. Waste treatment MUST BE PROCESSED THROUGH IN-HOUSE TREATMENT SECTION 12: Ecological information ECOTOXICITY DEGRADABILITY MOBILITY BIOACCUMULATIVE NO DATA NO DATA NO DATA NO DATA SECTION 13: Disposal considerations Sewage disposal AVOID CITY DRAINS SECTION 14: Transport information 14.1 UN Number 14.2 UN Proper Shipping Name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code None None None None None None None SECTION 15: Regulatory information Attention all Retailers of Mason Stains ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 using this material. OR BY REQUEST. Disclamer This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this SDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! SDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT SECTION 16: REFERENCE INFORMATION CPMA CLASSIFICATION AND CHEMICAL DESCRIPTIONS OF THE COMPLEX INORGANIC COLOR PIGMENTS Fourth Edition - January 2013 Update https://www.osha.gov/index.html http://chem.sis.nlm.nih.gov/chemidplus 13th Report on Carcinogens on October 2, 2014. http://monographs.iarc.fr/ENG/Classification/index.php Safety Data Sheet DATE PREPARED 4/28/2015 UPDATED 3/21/2016 6383 COBALT ALUMINATE BLUE SPINEL HMIS Classification: Health Flammability Reactivity 2* 0 0 Personal Protection See Section 8 1.1 Product identifier Product name COBALT ALUMINATE BLUE SPINEL varying amounts are homogeneously and ionically interdiffused to form a crystalline matrix of spinel. Its composition may include any one or a combination of the modifiers Li2O, MgO, SiO2, TiO2, or ZnO Cobalt Aluminate Blue Spinel, an inorganic pigment, is a reaction product of high temperature calcination in which Cobalt (II) Oxide, and Aluminum (III) Oxide in Product number EC no. CAS no. Index no. 1.4 Supplier’s details Name Address Telephone Fax 6383 COBALT ALUMINATE 310-193-6 1345-16-0 C.I. 77346 Mason Color Works Inc. 250 East Second Street East Livepool, Ohio 43920 USA 330 385 4400 330 385 4488 SECTION 2: Hazard Identification Signal Word: WARNING Not a hazardous substance GHS classification in accordance with OSHA (29 CFR 1910.1200) P261: Avoid breathing dust. H303: May be harmful if swallowed P262: Do not get in eyes, on skin. H313: May be harmful in contact with skin P264: Wash hands thoroughly after handling. H317: May cause an allergic skin reaction H333: May be harmful if inhaled H335: May cause respiratory irritation SECTION 3: Composition/information on ingredients COBALT ALUMINATE BLUE SPINEL C.I. Pigment Blue 28 100% EC no. CAS no. Index no. Formula 310-193-6 1345-16-0 C.I. 77346 CoAl2O4 SECTION 4: First-aid measures •Contact with skin: •Contact with eyes: •Swallowing: Wash with plenty of water and soap. Wash immediately with water for at least 10 minutes. Induce vomiting. SEEK A MEDICAL EXAMINATION IMMEDIATELY and present the safety-data sheet. A suspension of activated charcoal in water, or liquid paraffin may be administered. •Inhalation: Ventilate the premises. The patient is to be removed immediately from the contaminated premises and made to rest in a well ventilated area. Should the patient feel unwell, OBTAIN MEDICAL ATTENTION SECTION 5: Fire-fighting measures •Recommended extinguishers: •Extinguishers not to be used: •Risks arising from combustion: •Protective equipment: SECTION 6: Accidental release measures Water, CO2, Foam, Chemical powders, according to the materials involved in the fire. None in particular. Avoid inhaling the fumes. Use protection for the respiratory tract. •Measures for personal safety: •Environmental measures: . •Cleaning methods: Use gloves and protective clothing. In the event of particulates aerosols use respiratory protection. Keep away from drains, surface- and ground-water and soil Limit leakages with earth or sand. If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities. Remove the waste materials with a suitable device (for instance a suction pump) and dispose. After the product has been recovered, rinse the area and materials involved with water. •Handling precautions: Wear suitable gloves, glasses and face protection. Avoid contact and inhalation of the vapours/powders. SECTION 7: Handling and storage •Incompatible materials: •Storage conditions: •Instructions as regards storage premises: Do not eat or drink while working. None in particular. Always keep the containers tightly closed. Adequately ventilated premises. SECTION 8: Exposure controls / personal protection Cobalt, Metal, Dust & Fume (as Co) Aluminum (as Al), Metal (Total Dust) •Precautionary measures: •Respiratory protection: •Protection for hands: •Eye protection: •Protection for skin: ACGIH-TLVs 0.02 mg/m3 10 mg/mg3 (total) OSHA PELs 0.5 mg/m3 15 mg/m3 (total) 5 mg/m3 (respirable) NOISHA RELs N/A N/A Give adequate ventilation to the premises where the product is stored and/or handled. Use suitable respiratory protection. Not needed for normal use. Not needed for normal use. No special precaution must be adopted for normal use. SECTION 9: Physical and chemical properties Appearance/form Blue/Powder Flammability (solid, gas) none Upper/lower flammability limits Upper/lower explosive limits Odor pH SPECIFIC GRAVITY Flash point Evaporation rate Melting point/freezing point Initial boiling point and boiling range Vapor pressure Vapor density Relative density Solubility(ies) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties None 4.26 6.6 <1000 C NA NA NA NA NA NA NA NA NA NA NA NA none none insoluble SECTION 10: Stability and reactivity Chemical stability STABLE Possibility of hazardous reactions WILL NOT OCCUR Incompatible materials Hazardous decomposition products NONE N/A SECTION 11: Toxicological information INHALATION ORAL SKIN NON IRRITATING TO THE SKIN NON IRRITATING TO THE EYES LD50 (male rats) > 10000 mg/kg LC50 (rats; 4 hours) > >5.06 mg/L air N/A THIS PIGMENT IS NOT LISTED IN THE NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS. IT IS NOT LISTED AS A POTENTIAL CARCINOGEN IN THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER(IARC) MONOGRAPHS. IT IS NOT FOUND TO BE A CARCINOGEN BY THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION(OSHA) SECTION 12: Ecological information ECOTOXICITY DEGRADABILITY MOBILITY BIOACCUMULATIVE NO DATA NO DATA NO DATA NO DATA SECTION 13: Disposal considerations Disposal of the product Contain spillage and scoop or vacuum. Avoid making dust put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. Disposal of contaminated packaging Dispose of as unused product. Waste treatment MUST BE PROCESSED THROUGH IN-HOUSE TREATMENT Sewage disposal AVOID CITY DRAINS SECTION 14: Transport information 14.1 UN Number 14.2 UN Proper Shipping Name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code None None None None None None None SECTION 15: Regulatory information Attention all Retailers of Mason Stains ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 using this material. OR BY REQUEST. Disclamer This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT SECTION 16: REFERENCE INFORMATION CPMA CLASSIFICATION AND CHEMICAL DESCRIPTIONS OF THE COMPLEX INORGANIC COLOR PIGMENTS Fourth Edition - January 2013 Update https://www.osha.gov/index.html http://chem.sis.nlm.nih.gov/chemidplus 13th Report on Carcinogens on October 2, 2014. http://monographs.iarc.fr/ENG/Classification/index.php Product number 6385 PANSY PURPLE Safety Data Sheet DATE PREPARED: 5/20/2015 SECTION 1: Identification 6385 RED MIXTURE HMIS Classification: Health Flammability Reactivity 2* 0 0 Personal Protection See Section 8 1.4 Supplier’s details Name Address Telephone Fax Mason Color Works Inc. 250 East Second Street East Livepool, Ohio 43920 USA 330 385 4400 330 385 4488 SECTION 2: Hazard identification Classification of the substance or mixture GHS classification in accordance with OSHA (29 CFR 1910.1200) Not a hazardous substance or mixture. GHS label elements, including precautionary statements Not a hazardous substance or mixture. Other hazards which do not result in classificationNot a hazardous substance or mixture. SECTION 3: Composition/information on ingredients 6003 6388 CHROME TIN PINK SPHENE COBALT SILICATE BLUE OLIVINE % 89 11 EC no. 269-073-6 269-093-5 CAS no. 68187-12-2 68187-40-6 Index no. C.I. 77301 C.I. 77364 Formula CaO:SnO:SiO2:Cr2O3 Co2SiO4 C.I. Pigment Red 233 C. I. Pigment Blue 73 SECTION 4: First-aid measures •Contact with skin: •Contact with eyes: •Swallowing: Wash with plenty of water and soap. Wash immediately with water for at least 10 minutes. Induce vomiting. SEEK A MEDICAL EXAMINATION IMMEDIATELY and present the safety-data sheet. A suspension of activated charcoal in water, or liquid paraffin may be administered. •Inhalation: Ventilate the premises. The patient is to be removed immediately from the contaminated premises and made to rest in a well ventilated area. Should the patient feel unwell, OBTAIN MEDICAL ATTENTION SECTION 5: Fire-fighting measures •Recommended extinguishers: •Extinguishers not to be used: •Risks arising from combustion: •Protective equipment: Water, CO2, Foam, Chemical powders, according to the materials involved in the fire. None in particular. Avoid inhaling the fumes. Use protection for the respiratory tract. SECTION 6: Accidental release measures •Measures for personal safety: •Environmental measures: . •Cleaning methods: Use gloves and protective clothing. In the event of particulates aerosols use respiratory protection. Keep away from drains, surface- and ground-water and soil Limit leakages with earth or sand. If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities. Remove the waste materials with a suitable device (for instance a suction pump) and dispose. After the product has been recovered, rinse the area and materials involved with water. SECTION 7: Handling and storage •Handling precautions: Wear suitable gloves, glasses and face protection. Avoid contact and inhalation of the vapours/powders. •Incompatible materials: •Storage conditions: •Instructions as regards storage premises: Do not eat or drink while working. None in particular. Always keep the containers tightly closed. Adequately ventilated premises. SECTION 8: Exposure controls / personal protection Tin Oxide (as Sn) (Total Dust) Chromium (III) Compounds (as Cr) Cobalt, Metal, Dust & Fume (as Co) Silica, Crystalline (SiO2) ACGIH-TLVs 2.0 mg/m3 0.5 mg/m3 0.02 mg/m3 0.1 mg/m3 OSHA PELs 2.0 mg/m3 0.5 mg/m3 0.5 mg/m3 10 mg/m3 NOISHA RELs 2.0 mg/m3 0.5 mg/m3 N/A 0.05 mg/m3 Respiratory protection: Suitable respiratory protection for higher concentrations or long-term effect: Particle filter EN 143 Type P1, low efficiency, (solid particles of inert substances). Hand protection: Chemical resistant protective gloves (EN 374) e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Safety glasses with side-shields (frame goggles) (EN 166) General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Due to the colouring properties of the product closed work clothes should be used, to avoid stains during manipulation. Hands and/or face should be washed before breaks and at the end of the shift. SECTION 9: Physical and chemical properties Appearance/form RED/POWDER Odor pH SPECIFIC GRAVITY Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability limits Upper/lower explosive limits Vapor pressure Vapor density Relative density Solubility(ies) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties None 4.96 6 <1000 C none NA NA NA NA NA NA NA NA NA NA NA NA none none insoluble SECTION 10: Stability and reactivity Chemical stability STABLE Possibility of hazardous reactions WILL NOT OCCUR Incompatible materials Hazardous decomposition products NONE N/A SECTION 11: Toxicological information ORAL SKIN INHALATION LD50 (male and female rats) > 2200 mg/kg LC50 (male and female rats; 4 hours) > 5.4 mg/L UNKNOWN NON IRRITATING TO THE SKIN NON IRRITATING TO THE EYES THIS PIGMENT IS NOT LISTED IN THE NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS. IT IS NOT LISTED AS A POTENTIAL CARCINOGEN IN THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER(IARC) MONOGRAPHS. IT IS NOT FOUND TO BE A CARCINOGEN BY THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION(OSHA) SECTION 12: Ecological information ECOTOXICITY DEGRADABILITY MOBILITY BIOACCUMULATIVE NO DATA NO DATA NO DATA NO DATA SECTION 13: Disposal considerations Disposal of the product Contain spillage and scoop or vacuum. Avoid making dust put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. Disposal of contaminated packaging Dispose of as unused product. Waste treatment Sewage disposal MUST BE PROCESSED THROUGH IN-HOUSE TREATMENT AVOID CITY DRAINS SECTION 14: Transport information 14.1 UN Number 14.2 UN Proper Shipping Name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code None None None None None None None SECTION 15: Regulatory information Attention all Retailers of Mason Stains ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 using this material. OR BY REQUEST. Disclamer This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT SECTION 16: REFERENCE INFORMATION CPMA CLASSIFICATION AND CHEMICAL DESCRIPTIONS OF THE COMPLEX INORGANIC COLOR PIGMENTS Fourth Edition - January 2013 Update https://www.osha.gov/index.html http://chem.sis.nlm.nih.gov/chemidplus 13th Report on Carcinogens on October 2, 2014. http://monographs.iarc.fr/ENG/Classification/index.php Safety Data Sheet DATE PREPARED 4/28/2015 UPDATED 3/21/2016 6388 COBALT SILICATE BLUE OLIVINE HMIS Classification: Health Flammability Reactivity 1.1 Product identifier 2* 0 0 Personal Protection See Section 8 Product name COBALT SILICATE BLUE OLIVINE Cobalt Silicate Blue Olivine, an inorganic pigment, is a reaction product of high temperature calcination in which Cobalt (II) Oxide and Silicon (IV) Oxide in varying amounts are homogeneously and ionically interdiffused to form a crystalline matrix of olivine. Its composition may include any one or a combination of the modifiers Al2O3 , B203, CaO, PbO, or ZnO Product number EC no. CAS no. Index no. 1.4 Supplier’s details Name Address Telephone Fax 6388 MAZERINE 269-093-5 68187-40-6 C.I. 77364 Mason Color Works Inc. 250 East Second Street East Livepool, Ohio 43920 USA 330 385 4400 330 385 4488 SECTION 2: Hazard Identification Signal Word: WARNING Not a hazardous substance GHS classification in accordance with OSHA (29 CFR 1910.1200) P261: Avoid breathing dust. H303: May be harmful if swallowed P262: Do not get in eyes, on skin. H313: May be harmful in contact with skin P264: Wash hands thoroughly after handling. H317: May cause an allergic skin reaction H333: May be harmful if inhaled H335: May cause respiratory irritation SECTION 3: Composition/information on ingredients COBALT SILICATE BLUE OLIVINE C. I. Pigment Blue 73 100% EC no. CAS no. Index no. Formula 269-093-5 68187-40-6 C.I. 77364 Co2SiO4 SECTION 4: First-aid measures •Contact with skin: •Contact with eyes: •Swallowing: Wash with plenty of water and soap. Wash immediately with water for at least 10 minutes. Induce vomiting. SEEK A MEDICAL EXAMINATION IMMEDIATELY and present the safety-data sheet. A suspension of activated charcoal in water, or liquid paraffin may be administered. •Inhalation: Ventilate the premises. The patient is to be removed immediately from the contaminated premises and made to rest in a well ventilated area. Should the patient feel unwell, OBTAIN MEDICAL ATTENTION SECTION 5: Fire-fighting measures •Recommended extinguishers: •Extinguishers not to be used: •Risks arising from combustion: •Protective equipment: SECTION 6: Accidental release measures Water, CO2, Foam, Chemical powders, according to the materials involved in the fire. None in particular. Avoid inhaling the fumes. Use protection for the respiratory tract. •Measures for personal safety: •Environmental measures: . •Cleaning methods: Use gloves and protective clothing. In the event of particulates aerosols use respiratory protection. Keep away from drains, surface- and ground-water and soil Limit leakages with earth or sand. If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities. Remove the waste materials with a suitable device (for instance a suction pump) and dispose. After the product has been recovered, rinse the area and materials involved with water. SECTION 7: Handling and storage •Handling precautions: Wear suitable gloves, glasses and face protection. Avoid contact and inhalation of the vapours/powders. •Incompatible materials: •Storage conditions: •Instructions as regards storage premises: Do not eat or drink while working. None in particular. Always keep the containers tightly closed. Adequately ventilated premises. SECTION 8: Exposure controls / personal protection Cobalt, Metal, Dust & Fume (as Co) Silica, Crystalline (SiO2) •Precautionary measures: •Respiratory protection: •Protection for hands: •Eye protection: •Protection for skin: ACGIH-TLVs 0.02 mg/m3 0.1 mg/m3 OSHA PELs 0.5 mg/m3 10 mg/m3 NOISHA RELs N/A 0.05 mg/m3 Give adequate ventilation to the premises where the product is stored and/or handled. Use suitable respiratory protection. Not needed for normal use. Not needed for normal use. No special precaution must be adopted for normal use. SECTION 9: Physical and chemical properties Appearance/form PURPLE/ powder Flammability (solid, gas) none Upper/lower flammability limits Upper/lower explosive limits Odor pH SPECIFIC GRAVITY Flash point Evaporation rate Melting point/freezing point Initial boiling point and boiling range Vapor pressure Vapor density Relative density Solubility(ies) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties None 3.74 7.2 >1000c NA NA NA NA NA NA NA NA NA NA NA NA none none insoluble SECTION 10: Stability and reactivity Chemical stability Incompatible materials Hazardous decomposition products STABLE NONE N/A Possibility of hazardous reactions WILL NOT OCCUR SECTION 11: Toxicological information ORAL SKIN INHALATION NON IRRITATING TO THE SKIN NON IRRITATING TO THE EYES LD50 (male and female rats) = 1630 mg/kg (CL: 970 mg/kg - 3790 mg/kg) LC50 (male and female rats; 4 hours) > 5.3 mg/L N/A THIS PIGMENT IS NOT LISTED IN THE NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS. IT IS NOT LISTED AS A POTENTIAL CARCINOGEN IN THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER(IARC) MONOGRAPHS. IT IS NOT FOUND TO BE A CARCINOGEN BY THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION(OSHA) SECTION 12: Ecological information ECOTOXICITY DEGRADABILITY MOBILITY BIOACCUMULATIVE NO DATA NO DATA NO DATA NO DATA SECTION 13: Disposal considerations Disposal of the product Contain spillage and scoop or vacuum. Avoid making dust put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. Disposal of contaminated packaging Dispose of as unused product. Waste treatment Sewage disposal MUST BE PROCESSED THROUGH IN-HOUSE TREATMENT AVOID CITY DRAINS SECTION 14: Transport information 14.1 UN Number 14.2 UN Proper Shipping Name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code None None None None None None None SECTION 15: Regulatory information Attention all Retailers of Mason Stains ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 using this material. OR BY REQUEST. Disclamer This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT SECTION 16: REFERENCE INFORMATION CPMA CLASSIFICATION AND CHEMICAL DESCRIPTIONS OF THE COMPLEX INORGANIC COLOR PIGMENTS Fourth Edition - January 2013 Update https://www.osha.gov/index.html http://chem.sis.nlm.nih.gov/chemidplus 13th Report on Carcinogens on October 2, 2014. http://monographs.iarc.fr/ENG/Classification/index.php MULTIMAX™ Lite Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). Revision Date: 10/01/2019 Supersedes Date: 10/08/2018 Date of Issue: 05/24/2018 Version: 3.0 Company LATICRETE Canada ULC PO Box 129, Emeryville, Ontario, Canada N0R-1A0 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Mixture Product Name: MULTIMAX™ Lite 1.2. Intended Use of the Product Adhesive. For professional use only. 1.3. Name, Address, and Telephone of the Responsible Party Company LATICRETE International 1 Laticrete Park, N Bethany, CT 06524 T (203)-393-0010 www.laticrete.com 1.4. Emergency Telephone Number Emergency Number : For chemical emergency call ChemTel day or night: (800)255-3924 (North America) (800)-099-0731 (Mexico) +1 (813)248-0585 (International - collect calls accepted) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture GHS-US/CA Classification Skin Corr. 1C Eye Dam. 1 Skin Sens. 1 Carc. 1A STOT SE 3 Aquatic Acute 3 H314 H318 H317 H350 H335 H402 Full text of hazard classes and H-statements : see section 16 2.2. Label Elements GHS-US/CA Labeling Hazard Pictograms (GHS-US/CA) : Signal Word (GHS-US/CA) Hazard Statements (GHS-US/CA) : Danger : H314 - Causes severe skin burns and eye damage. GHS05 GHS07 GHS08 H317 - May cause an allergic skin reaction. H318 - Causes serious eye damage. H335 - May cause respiratory irritation. H350 - May cause cancer (Inhalation). H402 - Harmful to aquatic life. Precautionary Statements (GHS-US/CA) : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe dust, fume. P264 - Wash hands, forearms, and other exposed areas thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, and eye protection. EN (English US) 1/13 10/01/2019 MULTIMAX™ Lite Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 - If exposed or concerned: Get medical advice/attention. P310 - Immediately call a POISON CENTER or doctor. P321 - Specific treatment (see section 4 on this SDS). P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/container in accordance with local, regional, national, territorial, provincial, and international regulations. 2.3. Other Hazards Exposure may aggravate pre-existing eye, skin, or respiratory conditions. 2.4. Unknown Acute Toxicity (GHS-US/CA) No data available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Not applicable 3.2. Mixture Substance Name Cement, portland, chemicals Product Identifier (CAS-No.) 65997-15-1 % * 75.4-78.1 Calcium oxide (CAS-No.) 1305-78-8 41.5-54.7 Copolymer of vinyl acetate and ethylene with mineral additives and protective colloid Perlite Limestone Calicium Sulfate Hemihydrate Magnesium oxide (MgO) Calcium formate Quartz (CAS-No.) Not available 7-13 (CAS-No.) 93763-70-3 (CAS-No.) 1317-65-3 (CAS-No.) 13397-24-5 (CAS-No.) 1309-48-4 (CAS-No.) 544-17-2 (CAS-No.) 14808-60-7 7-13 3.8 - 3.9 3.8 - 3.9 2.26 - 2.34 0.1 - 2 0.75 – 0.78 Chromium, ion (Cr6+) (CAS-No.) 18540-29-9 0.00007 – 0.00008 GHS Ingredient Classification Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317 STOT SE 3, H335 Skin Irrit. 2, H315 Eye Dam. 1, H318 STOT SE 3, H335 Aquatic Acute 3, H402 Comb. Dust Not classified Not classified Not classified Not classified Eye Dam. 1, H318 Carc. 1A, H350 STOT SE 3, H335 STOT RE 1, H372 Skin Sens. 1, H317 Carc. 1B, H350 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Full text of H-phrases: see section 16 *Percentages are listed in weight by weight percentage (w/w%) for liquid and solid ingredients. Gas ingredients are listed in volume by volume percentage (v/v%). ** The actual concentration of ingredient(s) is withheld as a trade secret in accordance with the Hazardous Products Regulations (HPR) SOR/2015-17 and 29 CFR 1910.1200. 10/01/2019 EN (English US) 2/13 MULTIMAX™ Lite Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). SECTION 4: FIRST AID MEASURES 4.1. Description of First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Inhalation: Using proper respiratory protection, move the exposed person to fresh air at once. Encourage exposed person to cough, spit out, and blow nose to remove dust. Immediately call a poison center, physician, or emergency medical service. Skin Contact: Immediately remove contaminated clothing. Immediately flush skin with plenty of water for at least 30 minutes. Get immediate medical advice/attention. Eye Contact: Immediately rinse with water for at least 30 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention. Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most Important Symptoms and Effects Both Acute and Delayed General: Causes severe skin burns and eye damage. May cause respiratory irritation. May cause cancer (Inhalation). Inhalation: May be corrosive to the respiratory tract. Accelerated Silicosis can occur with exposure to high concentrations of respirable crystalline silica over a relatively short period; lung lesions can appear within five years of the initial exposure. The progression can be rapid. Accelerated silicosis is similar to chronic or ordinary silicosis, except that lung lesions appear earlier and the progression is more rapid. Acute Silicosis can occur with exposures to very high concentrations of respirable crystalline silica over a very short time period, sometimes as short as a few months. The symptoms of acute silicosis include progressive shortness of breath, fever, cough and weight loss. Acute silicosis can be fatal. Skin Contact: May cause an allergic skin reaction. Redness, pain, swelling, itching, burning, dryness, and dermatitis. Concrete may cause dry skin, discomfort, irritation, severe burns, and dermatitis. Unhardened concrete is capable of causing dermatitis by irritation and allergy. Concrete dust, in association with sweat and friction, can lead to skin irritation and dermatitis. Skin affected by dermatitis may include symptoms such as, redness, itching, rash, scaling, and cracking. Allergic contact dermatitis is caused by sensitization to hexavalent chromium (chromate) present in concrete. The reaction can range from a mild rash to severe skin ulcers. Eye Contact: Causes permanent damage to the cornea, iris, or conjunctiva. Concrete may cause immediate or delayed irritation or inflammation. Eye contact with wet concrete can cause moderate eye irritation, chemical burns and blindness. Eye exposures require immediate first aid and medical attention to prevent significant damage to the eye. Ingestion: May cause burns or irritation of the linings of the mouth, throat, and gastrointestinal tract. Chronic Symptoms: Causes damage to organs through prolonged or repeated exposure. May cause cancer. Repeated exposure to respirable (airborne) crystalline silica dust will cause lung damage in the form of silicosis. Some studies show that exposure to respirable crystalline silica (without silicosis) or that the disease silicosis may be associated with the increased incidence of several autoimmune disorders such as scleroderma (thickening of the skin), systemic lupus erythematosus, rheumatoid arthritis and diseases affecting the kidneys. Silicosis increases the risk of tuberculosis. Some studies show an increased incidence of chronic kidney disease and end-stage renal disease in workers exposed to respirable crystalline silica. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention. If medical advice is needed, have product container or label at hand. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. Reacts with water to form corrosive alkalis. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Not considered flammable but may burn at high temperatures. Explosion Hazard: Product is not explosive as supplied. However, when cured and dried this product may produce explosive combustible dust when cut, sanded, ground, or otherwise processed. Reactivity: Hydrofluoric acid will react with and dissolve glass, and other silica containing material. May react exothermically with water releasing heat. Adding an acid to a base or base to an acid may cause violent reaction. 5.3. Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Use water spray or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. 10/01/2019 EN (English US) 3/13 MULTIMAX™ Lite Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). Hazardous Combustion Products: None known. Reference to Other Sections Refer to Section 9 for flammability properties. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Do not breathe dust. Do not get in eyes, on skin, or on clothing. Avoid generating dust. Keep away from heat, hot surfaces, sparks, open flames, and other ignition sources. No smoking. 6.1.1. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protective equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. Ventilate area. 6.2. Environmental Precautions Prevent entry to sewers and public waters. Avoid release to the environment. 6.3. Methods and Materials for Containment and Cleaning Up For Containment: Contain solid spills with appropriate barriers and prevent migration and entry into sewers or streams. As an immediate precautionary measure, isolate spill or leak area in all directions. Avoid generation of dust during clean-up of spills. Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Vacuum clean-up is preferred. If sweeping is required use a dust suppressant. Avoid generation of dust during clean-up of spills. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. 6.4. Reference to Other Sections See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: May release corrosive vapors. Accumulation and dispersion of dust with an ignition source can cause a combustible dust explosion. Keep dust levels to a minimum and follow applicable regulations. Precautions for Safe Handling: Obtain special instructions before use. Do not breathe dust. Do not get in eyes, on skin, or on clothing. Do not handle until all safety precautions have been read and understood. Handle empty containers with care because they may still present a hazard. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Avoid creating or spreading dust. Proper grounding procedures to avoid static electricity should be followed. Storage Conditions: Keep container closed when not in use. Store in a dry, cool place. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials. Store locked up/in a secure area. Store in original container or corrosive resistant and/or lined container. Incompatible Materials: Strong acids, strong bases, strong oxidizers. Fluorinated compounds. Ammonia. Ammonium salts. Aluminum. 7.3. Specific End Use(s) Adhesive. For professional use only. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), OSHA (PEL), or Canadian provincial governments. Cement, portland, chemicals (65997-15-1) USA ACGIH ACGIH TWA (mg/m³) 1 mg/m³ (particulate matter containing no asbestos and <1% crystalline silica, respirable particulate matter) 10/01/2019 EN (English US) 4/13 MULTIMAX™ Lite Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). USA ACGIH USA OSHA USA NIOSH ACGIH chemical category OSHA PEL (TWA) (mg/m³) NIOSH REL (TWA) (mg/m³) USA IDLH Alberta British Columbia US IDLH (mg/m³) OEL TWA (mg/m³) OEL TWA (mg/m³) Manitoba OEL TWA (mg/m³) New Brunswick OEL TWA (mg/m³) Newfoundland & Labrador OEL TWA (mg/m³) Nova Scotia OEL TWA (mg/m³) Nunavut Nunavut Northwest Territories Northwest Territories Ontario OEL STEL (mg/m³) OEL TWA (mg/m³) OEL STEL (mg/m³) OEL TWA (mg/m³) OEL TWA (mg/m³) Prince Edward Island OEL TWA (mg/m³) Québec VEMP (mg/m³) Saskatchewan Saskatchewan Yukon Yukon OEL STEL (mg/m³) OEL TWA (mg/m³) OEL STEL (mg/m³) OEL TWA (mg/m³) Calcium oxide (1305-78-8) ACGIH TWA (mg/m³) USA ACGIH OSHA PEL (TWA) (mg/m³) USA OSHA USA NIOSH NIOSH REL (TWA) (mg/m³) USA IDLH US IDLH (mg/m³) OEL TWA (mg/m³) Alberta OEL TWA (mg/m³) British Columbia OEL TWA (mg/m³) Manitoba New Brunswick OEL TWA (mg/m³) Newfoundland & Labrador OEL TWA (mg/m³) OEL TWA (mg/m³) Nova Scotia OEL STEL (mg/m³) Nunavut OEL TWA (mg/m³) Nunavut OEL STEL (mg/m³) Northwest Territories OEL TWA (mg/m³) Northwest Territories OEL TWA (mg/m³) Ontario OEL TWA (mg/m³) Prince Edward Island VEMP (mg/m³) Québec Not Classifiable as a Human Carcinogen 15 mg/m³ (total dust) 5 mg/m³ (respirable fraction) 10 mg/m³ (total dust) 5 mg/m³ (respirable dust) 5000 mg/m³ 10 mg/m³ 1 mg/m³ (particulate matter containing no Asbestos and <1% Crystalline silica-respirable particulate) 1 mg/m³ (particulate matter containing no Asbestos and <1% Crystalline silica-respirable particulate matter) 10 mg/m³ (particulate matter containing no Asbestos and <1% Crystalline silica) 1 mg/m³ (particulate matter containing no Asbestos and <1% Crystalline silica-respirable particulate matter) 1 mg/m³ (particulate matter containing no Asbestos and <1% Crystalline silica-respirable particulate matter) 20 mg/m³ 10 mg/m³ 20 mg/m³ 10 mg/m³ 1 mg/m³ (containing no Asbestos and <1% Crystalline silica-respirable) 1 mg/m³ (particulate matter containing no Asbestos and <1% Crystalline silica-respirable particulate matter) 10 mg/m³ (containing no Asbestos and <1% Crystalline silica-total dust) 5 mg/m³ (containing no Asbestos and <1% Crystalline silica-respirable dust) 20 mg/m³ 10 mg/m³ 20 mg/m³ 30 mppcf 10 mg/m³ 2 mg/m³ 5 mg/m³ 2 mg/m³ 25 mg/m³ 2 mg/m³ 2 mg/m³ 2 mg/m³ 2 mg/m³ 2 mg/m³ 2 mg/m³ 4 mg/m³ 2 mg/m³ 4 mg/m³ 2 mg/m³ 2 mg/m³ 2 mg/m³ 2 mg/m³ 10/01/2019 EN (English US) 5/13 MULTIMAX™ Lite Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). OEL STEL (mg/m³) OEL TWA (mg/m³) OEL STEL (mg/m³) OEL TWA (mg/m³) Saskatchewan Saskatchewan Yukon Yukon Quartz (14808-60-7) ACGIH TWA (mg/m³) USA ACGIH ACGIH chemical category USA ACGIH OSHA PEL (TWA) (mg/m³) USA OSHA USA NIOSH NIOSH REL (TWA) (mg/m³) USA IDLH US IDLH (mg/m³) OEL TWA (mg/m³) Alberta OEL TWA (mg/m³) British Columbia OEL TWA (mg/m³) Manitoba New Brunswick OEL TWA (mg/m³) Newfoundland & Labrador OEL TWA (mg/m³) OEL TWA (mg/m³) Nova Scotia OEL TWA (mg/m³) Nunavut OEL TWA (mg/m³) Northwest Territories OEL TWA (mg/m³) Ontario OEL TWA (mg/m³) Prince Edward Island VEMP (mg/m³) Québec OEL TWA (mg/m³) Saskatchewan Yukon OEL TWA (mg/m³) Limestone (1317-65-3) USA OSHA OSHA PEL (TWA) (mg/m³) USA NIOSH NIOSH REL (TWA) (mg/m³) Alberta British Columbia British Columbia OEL TWA (mg/m³) OEL STEL (mg/m³) OEL TWA (mg/m³) New Brunswick OEL TWA (mg/m³) Nunavut Nunavut Northwest Territories Northwest Territories Québec Saskatchewan Saskatchewan Yukon Yukon OEL STEL (mg/m³) OEL TWA (mg/m³) OEL STEL (mg/m³) OEL TWA (mg/m³) VEMP (mg/m³) OEL STEL (mg/m³) OEL TWA (mg/m³) OEL STEL (mg/m³) OEL TWA (mg/m³) 4 mg/m³ 2 mg/m³ 4 mg/m³ 2 mg/m³ 0.025 mg/m³ (respirable particulate matter) A2 - Suspected Human Carcinogen 50 µg/m³ 0.05 mg/m³ (respirable dust) 50 mg/m³ (respirable dust) 0.025 mg/m³ (respirable particulate) 0.025 mg/m³ (respirable) 0.025 mg/m³ (respirable particulate matter) 0.1 mg/m³ (respirable fraction) 0.025 mg/m³ (respirable particulate matter) 0.025 mg/m³ (respirable particulate matter) 0.05 mg/m³ (respirable fraction) 0.05 mg/m³ (respirable fraction) 0.1 mg/m³ (designated substances regulation-respirable) 0.025 mg/m³ (respirable particulate matter) 0.1 mg/m³ (respirable dust) 0.05 mg/m³ (respirable fraction) 300 particle/mL 15 mg/m³ (total dust) 5 mg/m³ (respirable fraction) 10 mg/m³ (total dust) 5 mg/m³ (respirable dust) 10 mg/m³ 20 mg/m³ (total dust) 10 mg/m³ (total dust) 3 mg/m³ (respirable fraction) 10 mg/m³ (particulate matter containing no Asbestos and <1% Crystalline silica) 20 mg/m³ 10 mg/m³ 20 mg/m³ 10 mg/m³ 10 mg/m³ (Limestone, containing no Asbestos and <1% Crystalline silica-total dust) 20 mg/m³ 10 mg/m³ 20 mg/m³ 30 mppcf 10 mg/m³ Magnesium oxide (MgO) (1309-48-4) USA ACGIH USA ACGIH USA OSHA USA IDLH Alberta British Columbia ACGIH TWA (mg/m³) ACGIH chemical category OSHA PEL (TWA) (mg/m³) US IDLH (mg/m³) OEL TWA (mg/m³) OEL STEL (mg/m³) 10 mg/m³ (inhalable particulate matter) Not Classifiable as a Human Carcinogen 15 mg/m³ (fume, total particulate) 750 mg/m³ (fume) 10 mg/m³ (fume) 10 mg/m³ (respirable dust and fume) 10/01/2019 EN (English US) 6/13 MULTIMAX™ Lite Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). OSHA PEL (TWA) (mg/m³) 5 µg/m³ ACGIH TWA (mg/m³) OSHA PEL (TWA) (mg/m³) British Columbia OEL TWA (mg/m³) OEL TWA (mg/m³) Manitoba New Brunswick OEL TWA (mg/m³) Newfoundland & Labrador OEL TWA (mg/m³) OEL TWA (mg/m³) Nova Scotia OEL STEL (mg/m³) Nunavut OEL TWA (mg/m³) Nunavut OEL STEL (mg/m³) Northwest Territories OEL TWA (mg/m³) Northwest Territories OEL TWA (mg/m³) Ontario OEL TWA (mg/m³) Prince Edward Island VEMP (mg/m³) Québec OEL STEL (mg/m³) Saskatchewan OEL TWA (mg/m³) Saskatchewan OEL STEL (mg/m³) Yukon Yukon OEL TWA (mg/m³) Chromium, ion (Cr6+) (18540-29-9) USA OSHA Calicium Sulfate Hemihydrate (13397-24-5) USA ACGIH USA OSHA USA NIOSH NIOSH REL (TWA) (mg/m³) Alberta British Columbia British Columbia OEL TWA (mg/m³) OEL STEL (mg/m³) OEL TWA (mg/m³) Manitoba OEL TWA (mg/m³) Newfoundland & Labrador OEL TWA (mg/m³) OEL TWA (mg/m³) Nova Scotia OEL TWA (mg/m³) Ontario OEL TWA (mg/m³) Prince Edward Island VEMP (mg/m³) Québec Saskatchewan Saskatchewan Yukon Yukon Perlite (93763-70-3) USA OSHA USA NIOSH OEL STEL (mg/m³) OEL TWA (mg/m³) OEL STEL (mg/m³) OEL TWA (mg/m³) OSHA PEL (TWA) (mg/m³) NIOSH REL (TWA) (mg/m³) British Columbia OEL TWA (mg/m³) New Brunswick OEL TWA (mg/m³) Nunavut 10/01/2019 OEL STEL (mg/m³) 10 mg/m³ (fume, inhalable) 3 mg/m³ (respirable dust and fume) 10 mg/m³ (inhalable particulate matter) 10 mg/m³ (fume) 10 mg/m³ (inhalable particulate matter) 10 mg/m³ (inhalable particulate matter) 20 mg/m³ (inhalable fraction) 10 mg/m³ (inhalable fraction) 20 mg/m³ (inhalable fraction) 10 mg/m³ (inhalable fraction) 10 mg/m³ (inhalable) 10 mg/m³ (inhalable particulate matter) 10 mg/m³ (fume) 20 mg/m³ (inhalable fraction) 10 mg/m³ (inhalable fraction) 10 mg/m³ (fume) 10 mg/m³ (fume) 10 mg/m³ (inhalable particulate matter) 15 mg/m³ (total dust) 5 mg/m³ (respirable fraction) 10 mg/m³ (total dust) 5 mg/m³ (respirable dust) 10 mg/m³ 20 mg/m³ (total dust) 10 mg/m³ (total dust) 3 mg/m³ (respirable fraction) 10 mg/m³ (inhalable particulate matter) 10 mg/m³ (inhalable particulate matter) 10 mg/m³ (inhalable particulate matter) 10 mg/m³ (inhalable) 10 mg/m³ (inhalable particulate matter) 10 mg/m³ (containing no Asbestos and <1% Crystalline silica-total dust) 5 mg/m³ (containing no Asbestos and <1% Crystalline silica-respirable dust) 20 mg/m³ 10 mg/m³ 20 mg/m³ 30 mppcf 10 mg/m³ 15 mg/m³ (General Industry - total dust) 10 mg/m³ (total dust) 5 mg/m³ (respirable dust) 10 mg/m³ (total dust) 3 mg/m³ (respirable fraction) 10 mg/m³ (particulate matter containing no Asbestos and <1% Crystalline silica) 20 mg/m³ EN (English US) 7/13 MULTIMAX™ Lite Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). OEL TWA (mg/m³) Nunavut OEL STEL (mg/m³) Northwest Territories OEL TWA (mg/m³) Northwest Territories OEL STEL (mg/m³) Saskatchewan OEL TWA (mg/m³) Saskatchewan Yukon OEL TWA (mg/m³) Silica, crystalline (general form) (Not Applicable) USA OSHA OSHA PEL (TWA) (mg/m³) 10 mg/m³ 20 mg/m³ 10 mg/m³ 20 mg/m³ 10 mg/m³ 30 mppcf 50 µg/m³ (excludes construction work, agricultural operations, and exposures that result from the processing of sorptive clays) 8.2. Exposure Controls Appropriate Engineering Controls: Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are observed. Proper grounding procedures to avoid static electricity should be followed. Personal Protective Equipment: Gloves. Protective clothing. Protective goggles. Face shield. Insufficient ventilation: wear respiratory protection. Materials for Protective Clothing: Chemically resistant materials and fabrics. Corrosion-proof clothing. Hand Protection: Wear protective gloves. Eye and Face Protection: Chemical safety goggles and face shield. Skin and Body Protection: Wear suitable protective clothing. Respiratory Protection: If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn. In case of inadequate ventilation, oxygen deficient atmosphere, or where exposure levels are not known wear approved respiratory protection. Other Information: When using, do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State Appearance Odor Odor Threshold pH Evaporation Rate Melting Point Freezing Point Boiling Point Flash Point Auto-ignition Temperature Decomposition Temperature Flammability (solid, gas) Lower Flammable Limit Upper Flammable Limit Vapor Pressure Relative Vapor Density at 20°C Relative Density Specific Gravity Solubility Partition Coefficient: N-Octanol/Water Viscosity : Solid : Not available : Not available : Not available : Not available : Not available : Not available : Not available : Not available : Not available : Not available : Not available : Not available : Not available : Not available : Not available : Not available : Not available : Not available : Not available : Not available : Not available 10/01/2019 EN (English US) 8/13 MULTIMAX™ Lite Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity: Hydrofluoric acid will react with and dissolve glass, and other silica containing material. May react exothermically with water releasing heat. Adding an acid to a base or base to an acid may cause violent reaction. 10.2. Chemical Stability: Stable under recommended handling and storage conditions (see section 7). 10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. 10.4. Conditions to Avoid: Direct sunlight, extremely high or low temperatures, and incompatible materials. Sparks, heat, open flame and other sources of ignition. Dust accumulation. 10.5. Incompatible Materials: Strong acids, strong bases, strong oxidizers. Fluorinated compounds. Ammonia. Ammonium salts. Aluminum. 10.6. Hazardous Decomposition Products: Metal oxides. Sulfur oxides. Carbon oxides (CO, CO2). SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects - Product Acute Toxicity (Oral): Not classified Acute Toxicity (Dermal): Not classified Acute Toxicity (Inhalation): Not classified LD50 and LC50 Data: Not available Skin Corrosion/Irritation: Causes severe skin burns and eye damage. Eye Damage/Irritation: Causes serious eye damage. Respiratory or Skin Sensitization: May cause an allergic skin reaction. Germ Cell Mutagenicity: Not classified Carcinogenicity: May cause cancer (Inhalation). Specific Target Organ Toxicity (Repeated Exposure): Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation. Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: May be corrosive to the respiratory tract. Accelerated Silicosis can occur with exposure to high concentrations of respirable crystalline silica over a relatively short period; lung lesions can appear within five years of the initial exposure. The progression can be rapid. Accelerated silicosis is similar to chronic or ordinary silicosis, except that lung lesions appear earlier and the progression is more rapid. Acute Silicosis can occur with exposures to very high concentrations of respirable crystalline silica over a very short time period, sometimes as short as a few months. The symptoms of acute silicosis include progressive shortness of breath, fever, cough and weight loss. Acute silicosis can be fatal. Symptoms/Injuries After Skin Contact: May cause an allergic skin reaction. Redness, pain, swelling, itching, burning, dryness, and dermatitis. Concrete may cause dry skin, discomfort, irritation, severe burns, and dermatitis. Unhardened concrete is capable of causing dermatitis by irritation and allergy. Concrete dust, in association with sweat and friction, can lead to skin irritation and dermatitis. Skin affected by dermatitis may include symptoms such as, redness, itching, rash, scaling, and cracking. Allergic contact dermatitis is caused by sensitization to hexavalent chromium (chromate) present in concrete. The reaction can range from a mild rash to severe skin ulcers. Symptoms/Injuries After Eye Contact: Causes permanent damage to the cornea, iris, or conjunctiva. Concrete may cause immediate or delayed irritation or inflammation. Eye contact with wet concrete can cause moderate eye irritation, chemical burns and blindness. Eye exposures require immediate first aid and medical attention to prevent significant damage to the eye. Symptoms/Injuries After Ingestion: May cause burns or irritation of the linings of the mouth, throat, and gastrointestinal tract. Chronic Symptoms: Causes damage to organs through prolonged or repeated exposure. May cause cancer. Repeated exposure to respirable (airborne) crystalline silica dust will cause lung damage in the form of silicosis. Some studies show that exposure to respirable crystalline silica (without silicosis) or that the disease silicosis may be associated with the increased incidence of several autoimmune disorders such as scleroderma (thickening of the skin), systemic lupus erythematosus, rheumatoid arthritis and diseases affecting the kidneys. Silicosis increases the risk of tuberculosis. Some studies show an increased incidence of chronic kidney disease and end-stage renal disease in workers exposed to respirable crystalline silica. 11.2. Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data: Calcium oxide (1305-78-8) LD50 Oral Rat LD50 Dermal Rabbit 10/01/2019 > 2000 mg/kg > 2500 mg/kg EN (English US) 9/13 MULTIMAX™ Lite Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). > 5000 mg/kg > 5000 mg/kg 3870 mg/kg 12960 mg/kg (Mouse) 1 Known Human Carcinogens. In OSHA Hazard Communication Carcinogen list. 1 In OSHA Hazard Communication Carcinogen list. In OSHA Specifically Regulated Carcinogen list. 3 1 Known Human Carcinogens. In OSHA Hazard Communication Carcinogen list. In OSHA Specifically Regulated Carcinogen list. 36.2 mg/l (Exposure time: 96 h - Species: Pimephales promelas) 7.6 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss) Quartz (14808-60-7) LD50 Oral Rat LD50 Dermal Rat Magnesium oxide (MgO) (1309-48-4) LD50 Oral Rat Perlite (93763-70-3) LD50 Oral Rat Quartz (14808-60-7) IARC Group National Toxicology Program (NTP) Status OSHA Hazard Communication Carcinogen List Chromium, ion (Cr6+) (18540-29-9) IARC Group OSHA Hazard Communication Carcinogen List OSHA Specifically Regulated Carcinogen List Sepiolite (Mg2H2(SiO3)3.xH2O) (63800-37-3) IARC Group Silica, crystalline (general form) (Not Applicable) IARC Group National Toxicology Program (NTP) Status OSHA Hazard Communication Carcinogen List OSHA Specifically Regulated Carcinogen List SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecology - General: Harmful to aquatic life. Calcium oxide (1305-78-8) LC50 Fish 1 Chromium, ion (Cr6+) (18540-29-9) LC50 Fish 1 LC50 Fish 2 12.2. Persistence and Degradability 50.6 mg/l MULTIMAX™ Lite Persistence and Degradability 12.3. Bioaccumulative Potential Not established. MULTIMAX™ Lite Bioaccumulative Potential Calcium oxide (1305-78-8) BCF Fish 1 Not established. (no bioaccumulation) 12.4. Mobility in Soil 12.5. Other Adverse Effects Other Information: Avoid release to the environment. Not available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of contents/container in accordance with local, regional, national, territorial, provincial, and international regulations. Ecology - Waste Materials: Avoid release to the environment. This material is hazardous to the aquatic environment. Keep out of sewers and waterways. SECTION 14: TRANSPORT INFORMATION The shipping description(s) stated herein were prepared in accordance with certain assumptions at the time the SDS was authored, and can vary based on a number of variables that may or may not have been known at the time the SDS was issued. 10/01/2019 EN (English US) 10/13 MULTIMAX™ Lite Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). Health hazard - Specific target organ toxicity (single or repeated exposure) Health hazard - Carcinogenicity Health hazard - Respiratory or skin sensitization Health hazard - Serious eye damage or eye irritation Health hazard - Skin corrosion or Irritation WARNING: This product contains chemicals known to the State of California to cause cancer. WARNING: This product contains chemicals known to the State of California to cause cancer. WARNING: This product contains chemicals known to the State of California to cause birth defects. WARNING: This product contains chemicals known to the State of California to cause cancer. 14.1. In Accordance with DOT Not regulated for transport 14.2. In Accordance with IMDG Not regulated for transport 14.3. In Accordance with IATA Not regulated for transport 14.4. In Accordance with TDG Not regulated for transport SECTION 15: REGULATORY INFORMATION 15.1. US Federal Regulations MULTIMAX™ Lite SARA Section 311/312 Hazard Classes Cement, portland, chemicals (65997-15-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory Calcium oxide (1305-78-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory Quartz (14808-60-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory Limestone (1317-65-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Magnesium oxide (MgO) (1309-48-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. US State Regulations Quartz (14808-60-7) U.S. - California - Proposition 65 - Carcinogens List Chromium, ion (Cr6+) (18540-29-9) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity Silica, crystalline (general form) U.S. - California - Proposition 65 - Carcinogens List Cement, portland, chemicals (65997-15-1) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Calcium oxide (1305-78-8) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Quartz (14808-60-7) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Limestone (1317-65-3) 10/01/2019 EN (English US) 11/13 MULTIMAX™ Lite Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Magnesium oxide (MgO) (1309-48-4) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Chromium, ion (Cr6+) (18540-29-9) U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Calicium Sulfate Hemihydrate (13397-24-5) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Perlite (93763-70-3) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List 15.3. Canadian Regulations Cement, portland, chemicals (65997-15-1) Listed on the Canadian DSL (Domestic Substances List) Calcium oxide (1305-78-8) Listed on the Canadian DSL (Domestic Substances List) Quartz (14808-60-7) Listed on the Canadian DSL (Domestic Substances List) Limestone (1317-65-3) Listed on the Canadian NDSL (Non-Domestic Substances List) Magnesium oxide (MgO) (1309-48-4) Listed on the Canadian DSL (Domestic Substances List) Calicium Sulfate Hemihydrate (13397-24-5) Listed on the Canadian DSL (Domestic Substances List) Perlite (93763-70-3) Listed on the Canadian DSL (Domestic Substances List) Water (7732-18-5) Listed on the Canadian DSL (Domestic Substances List) SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Date of Preparation or Latest Revision Other Information : 10/01/2019 : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 and Canada’s Hazardous Products Regulations (HPR) SOR/2015-17. GHS Full Text Phrases: ------ Acute Tox. 3 (Inhalation:dust,mist) ------ Aquatic Acute 1 ------ Aquatic Acute 3 ------ Aquatic Chronic 1 ------ Carc. 1 ------ Carc. 1A ------ Carc. 1B ------ Comb. Dust Eye Dam. 1 ------ Acute toxicity (inhalation:dust,mist) Category 3 Hazardous to the aquatic environment - Acute Hazard Category 1 Hazardous to the aquatic environment - Acute Hazard Category 3 Hazardous to the aquatic environment - Chronic Hazard Category 1 Carcinogenicity, Category 1 Carcinogenicity Category 1A Carcinogenicity Category 1B Combustible Dust Serious eye damage/eye irritation Category 1 10/01/2019 EN (English US) 12/13 MULTIMAX™ Lite Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations And According To The Hazardous Products Regulation (February 11, 2015). Skin Corr. 1C Skin Irrit. 2 Skin Sens. 1 STOT RE 1 STOT SE 3 ------ ------ ------ ------ ------ ------ H314 ------ H315 ------ H317 ------ H318 ------ H331 ------ H335 ------ H350 ------ H372 ------ H400 ------ H402 ------ H410 Skin corrosion/irritation Category 1C Skin corrosion/irritation Category 2 Skin sensitization, Category 1 Specific target organ toxicity (repeated exposure) Category 1 Specific target organ toxicity (single exposure) Category 3 Causes severe skin burns and eye damage Causes skin irritation May cause an allergic skin reaction Causes serious eye damage Toxic if inhaled May cause respiratory irritation May cause cancer Causes damage to organs through prolonged or repeated exposure Very toxic to aquatic life Harmful to aquatic life Very toxic to aquatic life with long lasting effects This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. NA GHS SDS 2015 (Can, US) 10/01/2019 EN (English US) 13/13 STANDARD CLAY COMPANY P.O. Box 16240 Pittsburgh, PA 15242-0240 SAFETY DATA SHEET Section 1: IDENTIFICATION Product Name: 798 Black Sculpture Clay with Grog Company Name: Telephone: Emergency Telephone: Recommended use of product: Standard Clay Company 24 Chestnut Street Carnegie, PA 15106-2028Technical@standardclay.com 412-276-6333 911 Ceramic ware Section 2: HAZARDS IDENTIFICATION Contains Crystalline Silica >1% Respirable GHS Label elements/Hazard Pictograms Signal Word: Danger OSHA/HCS status: Clay mixture in dry form is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) Classification of the substance: Hazard Statement: Carcinogenicity (inhalation) - Category 1A and Specific organ toxicity (Repeated substance or mixture: Exposure) (Respiratory tract through inhalation) - Category 1 (H350) Cancer Hazard. Contains quartz (crystalline silica) which may cause cancer. Risk of cancer depends upon duration and level of exposure to the dust. Not an acute hazard. (H332) Prolonged inhalation of dust may cause lung injury. Inhalation of high concentrations of dust may cause mechanical irritation and discomfort of the respiratory tract. Repeated exposure may have chronic effects. (H316 + H320 + H335) Can cause skin, respiratory, and eye irritation. Page | 1 STANDARD CLAY COMPANY P.O. Box 16240 Pittsburgh, PA 15242-0240 Precautionary Statements: Contains Crystalline Silica ≥1% Respirable (P261) Avoid breathing dust. (P280) Wear protective gloves, eye, and respiratory protection. Section 3: COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENTS CAS NUMBER % OF FORMULA Kaolin/Clay Crystalline silica Mullite Feldspar 1332-58-7 14808-60-7 68476-25-5 7439-96-5 0% - 50% 0% - 40% 0% - 35% 0-15% Section 4: FIRST-AID MEASURES DESCRIPTION OF FIRST-AID MEASURES Symptoms and Effects, both Acute and Delayed Contact a physician immediately. May cause irritation; remove from exposure. May cause irritation; rinse skin with soap and water. May cause irritation; flush eyes with water for at least 15 minutes. If irritation continues afterwards, contact a physician. Prolonged contact with large amounts of dust may cause mechanical irritation. Prolonged contact with large amounts of dust may cause mechanical irritation Ingestion: Inhalation: Skin Contact: Eye Contact: Eye Contact: Skin Contact: Page | 2 Inhalation: Chronic Symptoms: STANDARD CLAY COMPANY P.O. Box 16240 Pittsburgh, PA 15242-0240 Inhalation of high concentrations of dry clay dust may cause mechanical irritation and discomfort. Long term exposure may cause chronic effects (see section 11). Repeated or prolonged exposure to respirable crystalline silica dust may cause lung damage in the form of silicosis. Symptoms will include shortness of breath, fever, fatigue, loss of appetite, chest pain, dry non- productive cough. Ingestion: Large quantities ingested may cause gastrointestinal irritation. Section 5: FIRE-FIGHTING MEASURES General Fire Hazards: Clay mixture in dry or moist form is not flammable and does not support fire. The paper bags or plastic bags and cardboard boxes containing the mixture are flammable. Extinguishing Media: Use appropriate extinguishing media for surrounding fire. Chemical Hazards from fire: Clay mixture does not contain hazardous decomposition products. Protective actions and Equipment for Fire-fighters: Clay mixtures and packaging can become slippery when wet. Fire- fighters should wear appropriate protective equipment. Section 6: ACCIDENTAL RELEASE MEASURES Clean-up Methods If appropriate, use gentle spray to down and minimize dust generation. Personal Precautions, Protective Equipment: Wear appropriate protective equipment and clothing during clean- up. When dry sweeping use NIOSH approved respirators when dust levels exceed exposure limits Page | 3 STANDARD CLAY COMPANY P.O. Box 16240 Pittsburgh, PA 15242-0240 Environmental Precautions: Clay is a natural mineral product mixture and will not cause adverse effects to the water system other than turbidity from suspended particles. Methods and Materials for Containment and Clean up: Clean up any wet spills or clay slop with a damp sponge. For dry spills, spray with water and use a damp sponge to clean up. Section 7: HANDLING AND STORAGE Precautions for Safe Handling and Use: Use proper lifting techniques to avoid physical injury. Conditions for Safe Storage: No special storage considerations. Do not store moist clay mixture below freezing point. Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION AIRBORNE EXPOSURE LIMITS Ingredients OSHA PEL/ACGIH TLV Kaolin/Clay 5mg/m3 / 2mg/m3 respirable Crystaline silica- quartz 0.1 mg/m3 / 0.025mg /m3 respirable Mullite Feldspar 5mg/m3 / 2mg/m3 respirable 5mg/m3 / 2mg/m3 respirable Engineering Measures Page | 4 STANDARD CLAY COMPANY P.O. Box 16240 Pittsburgh, PA 15242-0240 Clay mixture in moist form poses no inhalation health risk. Once clay mixture has dried, there may be dust generated by cleaning and working processes. In the event that dust is generated, use local exhaust ventilation or other engineering controls as required to maintain exposures below applicable occupational exposure limits (TLV). Personal Protective Equipment (PPE) Respiratory protection: Dust is generated when working with dry clay mixture. To minimize exposure to dust and/or crystalline silica, cutting or sanding dry clay products should be conducted with sufficient ventilation. Respirable dust and quartz levels should be monitored regularly. Dust and quartz levels in excess of appropriate exposure limits should be reduced by feasible engineering controls, including (but not limited to) wet sanding, wet suppression, ventilation, and process enclosure. When such controls are not feasible, NIOSH/MSHA approved respirators must be worn in accordance with a respiratory protection program which meets OSHA requirements as set forth at 29 CFR1910.134 and ANSI Z88.2-1080 "Practices for Respiratory Protection”. In most cases, a disposable N-95 Particulate Respirator is sufficient.. Use of NIOSH/OSHA approved safety glasses with side shields is recommended. Face shields should also be used when dry sawing clay products. Wear tight fitting dust goggles when excessively (visible) dusty conditions are present or are anticipated. NIOSH recommends that contact lenses not be worn when working with crystalline silica dust. Protective Clothing is not essential. Use gloves and/or protective clothing if abrasion or allergic reactions are experienced. Food, beverages, and smoking materials should not be in work area. Employees should wash hands thoroughly before eating, drinking, or smoking. Eyes: Skin protection: Hygienic Practices: Page | 5 STANDARD CLAY COMPANY P.O. Box 16240 Pittsburgh, PA 15242-0240 Negligible Solid None None N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A None N/A None N/A Section 9: PHYSICAL/CHEMICAL PROPERTIES Appearance (physical state, color, etc.): Upper/lower flammability or explosive limits: Odor: Vapor pressure: Odor threshold : Vapor density: pH: Relative density: Freezing point: Solubility(ies): Page | 6 Initial boiling point and boiling range: Flash Point: Evaporation rate: Flammability (solid gas): Partition coefficient: n-octanol/water: Auto-ignition temperature: Decomposition temperature: Viscosity : Section 10 : STABILITY /REACTIVITY Reactivity: No dangerous reactions are known under normal conditions. Chemical stability: Stable at standard temperature and pressure. No stabilizers required to maintain chemical stability. Safety issues - Mold may STANDARD CLAY COMPANY P.O. Box 16240 Pittsburgh, PA 15242-0240 form in plastic bag (moist clay mixture) after several months of shelf life. Possibility of hazardous reactions: None known Conditions to avoid: Incompatibility/ Hazardous decomposition products: None known None known Section 11: TOXICOLGICAL INFORMATION Primary Route of Exposure: Skin, Eye Contact, Inhalation and Ingestion Specific Organ Toxicity - Single Exposure: Target organs include ears, skin, respiratory system, and gastrointestinal tract. Specific Organ Toxicity - Repeated Exposure: Causes damage to eyes, skin, respiratory system, and gastrointestinal tract through prolonged or repeated exposure. Acute Short-Term Exposure Effects: May cause eye irritation, skin irritation, respiratory tract irritation, and gastrointestinal tract irritation. Inhalation of high concentrations of dry clay dust may cause mechanical irritation and discomfort. Long term exposure may cause chronic effects. Chronic Long Term Exposure Effects: Silica has been classified by OSHA as a human lung carcinogen. Repeated or prolonged exposure of respirable crystalline silica dust may cause lung damage in the form of silicosis. Effects of silicosis include bronchitis/chronic obstructive pulmonary disorder, increased susceptibility to tuberculosis, scleroderma (a disease affecting skin, blood vessels, joints and skeletal muscles), and possible renal disease. Acute silicosis can be fatal. Related Symptoms: Symptoms will include shortness of breath, fever, fatigue, loss of appetite, chest pain, dry non-productive cough. Medical Conditions Aggravated by Exposure: Individuals with pre-existing allergies, eye disorders, skin disorders, respiratory disorders and/or gastrointestinal disorders may have increased susceptibility to the effects of exposure. Page | 7 STANDARD CLAY COMPANY P.O. Box 16240 Pittsburgh, PA 15242-0240 OSHA, IARC, and NTP Carcinogen Classifications Chemicals with Carcinogen Potential CAS # OSHA IARC NTP Crystaline Silica - quartz 14808-60-7 YES Cristobalite 14464-46-1 YES YES - 1 YES - 1 YES YES IARC - International Agency for Research on Cancer 1 = Carcinogenic to humans 2A = Probably carcinogenic to humans 2B = Possibly carcinogenic to humans OSHA - Occupational Safety & Health Administration NTP - National Toxicology Program Section 12: ECOLOGICAL INFORMATION (non-mandatory) Eco toxicity: None Persistence and degradability: Yes Bioaccumulation potential: No Mobility in soil: No Other adverse environmental effects: None Section 13: DISPOSAL CONSIDERATIONS (non-mandatory) Handling for Disposal: None Methods of Disposal: None Section 14: TRANSPORT INFORMATION (non-mandatory) UN Shipping Name: N/A UN Number: N/A Environmental Hazard: None Packing Group: None Transportation Hazard Class: N/A Special Precautions: None NOT DANGEROUS FOR TRANSPORT Page | 8 STANDARD CLAY COMPANY P.O. Box 16240 Pittsburgh, PA 15242-0240 Section 15: REGULATORY INFORMATION (non-mandatory) Silica (Quartz) is listed by California, Proposition 65, as a carcinogen. Silica (Quartz) is listed on the IARC, OSHA, and NTP carcinogen list. All ingredients are on U.S. TSCA Inventory. All products listed in this SDS conform to ASTM-4236 standards. Materials have been evaluated under the provisions of 16 CFR 1500.14 of the Labeling of Hazardous Art Material Act. These products have been listed as non-toxic and non-flammable under proposed use conditions. No specific warning is required. Section 16: OTHER INFORMATION This information is furnished without warranty, representation, inducement or license or any kind, except that it is accurate to the best of knowledge of Standard Clay Company or obtained from other references and sources believed to be accurate. Standard Clay Company does not assume any legal responsibility for use or reliance on our products. Customers are encouraged to conduct their own tests before using any product. Read all product labels prior to handling. Preparation date: 02/04/2023 Page | 9 U.S. SILICA COMPANY Safety Data Sheet European Union Page 1 of 10 Product Name: Silica Sand and Ground Silica Product Description: Crystalline Silica 1. Identification of the substance/preparation and of the company/undertaking Company / Producer Use of the substance/preparation Identification of the substance or preparation 1.1. Product Name/Trade Names: Sand and Ground Silica Sand (flour) sold under various names: ASTM TESTING SANDS • GLASS SAND • FLINT SILICA • DM-SERIES • F-SERIES • FOUNDRY SANDS • FJ-SERIES • H-SERIES • L-SERIES • N-SERIES • NJ SERIES • OK-SERIES • P-SERIES • T-SERIES • HYDRAULIC FRACING SANDS • MIN-U-SIL® Fine Ground Silica • MYSTIC WHITE® • #1 DRY • #1 SPECIAL • PENN SAND® • Q-ROK® • SIL-CO-SIL® Ground Silica • MICROSIL® • Supersil® • MASON SAND • GS SERIES • PER-SPEC Chemical Name or Synonym: Silicon Dioxide (SiO2). Sand, Silica Sand, Quartz, Crystalline Silica, Flint, Ground Silica (flour). White or tan sand or ground silica with no odor. 1.2. Main Applications (non-exhaustive list): abrasives, brick, ceramics, foundry castings, glass, grout, hydraulic frac (proppant) sand, mortar, paint and coatings, silicate chemistry, silicone rubber, thermoset plastics. 1.3. U.S. Silica Company 8490 Progress Drive, Suite 300 Frederick, MD 21701 U.S.A. 301-682-0600 For all sand & ground silica products: Active Minerals International, LLC 6 North Park Drive – Suite 105 Hunt Valley, MD 21030 U.S.A. Contact: Terri Kansler Telephone: 410-825-2920 T.Kansler@activeminerals.com 1.4. (office hours only) Contact: Terri Kansler Telephone: 410-825-2920 Emergency telephone Page 2 of 10 U.S. SILICA COMPANY Safety Data Sheet European Union Silica Sand and Ground Silica 2. Hazards Identification Silica sand is not per se hazardous. However, any particles at sizes below 10 micron are respirable and may penetrate the lungs. As the products identified in this safety data sheet may contain more than 10% of particles below 10 micron, the preparation is classified as “harmful” Xn R48/20 according to Directives 67/548/EEC and 1999/45/EC. The mixture is classified as STOT RE 1/ H372/ P260, P285, P501 according to the CLP (Hazard Class/Hazard Statement/Precaution Statements): Prolonged inhalation of excessive levels of respirable crystalline silica dust may cause silicosis, a lung fibrosis. Individuals with silicosis are reported to have an increased risk of lung cancer. Principal symptoms of silicosis are cough and breathlessness. Exposure to dust should be monitored and managed. Hazardous Decomposition or Byproducts: Silica will dissolve in hydrofluoric acid and produce a corrosive gas – silicon tetrafluoride. 3. Composition / Information on Ingredients Component / CAS # Symbol Risk EC # % Crystalline Silica (quartz) 14808-60-7 238-878-4 98.7 - 99.9 Per EU 67/548/EEC (DSD), XN R48/20 Per EN 1272/2008 (CLP) Hazard Class / Hazard Statement/ Precaution Statements 1344-28-1 None None 1309-37-1 13463-67-7 None Aluminum Oxide Iron Oxide Titanium Oxide STOT RE1 None None None 215-691-6 215-168-2 236-675-5 <1.1 <0.1 <0.1 Phrases H372 / P260, P285, P501 4. First Aid Measures 4.1. 4.2. 4.3. 4.4. Skin Exposure: Not applicable Ingestion: Not applicable Eye Exposure: Wash immediately with plenty of water. If irritation persists, seek medical attention. Inhalation: No specific first-aid is necessary since the adverse health effects associated with exposure to crystalline silica (quartz) result from chronic exposures. If there is a gross inhalation of crystalline silica (quartz), remove the person immediately to fresh air, give artificial respiration as needed, seek medical attention as needed. Page 3 of 10 U.S. SILICA COMPANY Safety Data Sheet European Union Silica Sand and Ground Silica 5. Fire Fighting Measures 5.1. Fire Hazard Data: Autoignition: Not Applicable Flash Point: Not Applicable Flammability Limits (vol / vol%): Lower: Not Applicable Upper: Not Applicable Extinguishing Media: Product is not flammable, combustible or explosive. Use extinguishing media appropriate for surrounding fire. Special Fire Fighting Procedures: Use self contained breathing apparatus with full face mask. Unusual Fire and Explosion Hazards: None 6. Accidental Release Measures Personal precautions: Avoid dust formation. In case of dust exposure, wear protective equipment specified in Section 8 of this Safety Data Sheet. Environmental precautions: No specific precautions. Discard any product, residue, disposable container or liner in compliance with regulatory requirements. Methods for cleaning up: Avoid dry sweeping. Use water spraying / flushing or ventilated vacuum cleaning system. Use closed containers. 7. Handling and Storage Handling Avoid dust formation. Do not breathe dust. Use adequate exhaust ventilation and dust collection. Keep airborne dust concentrations below permissible national exposure limits. Do not rely on your sight to determine if dust is in the air. Respirable crystalline silica dust may be in the air without a visible dust cloud. In case of insufficient ventilation , wear a respirator approved for silica dust when using, handling, storing or disposing of this product or bag. Practice good housekeeping. Do not permit dust to collect on walls, floors, sills, ledges, machinery, or equipment. Maintain, clean, and fit test respirators in accordance with EN standards. Maintain and test ventilation and dust collection equipment. Wash or vacuum clothing that has become dusty. 6.1. 7.1. U.S. SILICA COMPANY Safety Data Sheet European Union Silica Sand and Ground Silica Page 4 of 10 DO NOT USE U.S. SILICA COMPANY MATERIALS FOR SAND BLASTING. Storage Ensure trapping of dust produced during loading and unloading. Keep containers closed and store bags as to avoid accidental bursting. Specific uses Apply safe handling recommendations in Section 7.1. 8. Exposure Controls / Personal Protection Exposure limit values 7.2. 7.3. 8.1. Crystalline Silica Austria Occupational Exposure Limit Maximale Arbeitsplatzkonzentration 0.15/mg/m3 0.1 mg/m3 VLE (respirable dust) 0.07 mg/m3 (OEL (8 h) respirable fraction) 10% of respirable crystalline silica in air sample Czech Republic 0.1 mg/m3 Denmark 0.1 mg/m3 TWA (total); 0.1 mg/m3 TWA (respirable) 0.1 mg/m3 TWA (respirable dust) 0.2 mg/m3 TWA (respirable); 0.2 mg/m3 TWA (blasting and quarrying, respirable) 0.1 mg/m3 VME (inhalable fraction, listed under silica crystallines). In addition, separate reference value for dust (5 or 25k/Q) Previously maximale Arbeitsplatzkonzentration 0.15mg/m3. Since 2005 workers health protection system (“Schutzstufenkonzept”) 0.1 mg/m3 Hungary 0.15 mg/m3 TWA (respirable) Ireland 0.05mg/m3 2002 Code of practice for Safety Health & Welfare at Work 0.05 mg/m3 Associazone Italiana Degli Igienisti Industriali 1 mg/m3 (if silicon dioxide is more than 70%) 2 mg/m3 (if silicon dioxide is 10 - 70%) 4 mg/m3 (if silicon dioxide is 2 - 10%) 0.1 mg/m3 IPRV (respirable fraction), general dust respirable fraction 10 mg/m3 and alveolar fraction 5 mg/m3 0.15 mg/m3 None for respirable crystalline silica. In specific situations, Maltese authorities are in practice applying UK reference values. 0.075 mg/m3 MAC (respirable dust) Belgium Bulgaria Cyprus Estonia Finland France Germany Greece Italy Latvia Lithuania Luxembourg Malta Netherlands U.S. SILICA COMPANY Safety Data Sheet European Union Silica Sand and Ground Silica Page 5 of 10 Poland 2 mg/m3 NDS (total inhalable dust, containing >50% free crystalline silica); 0.3 mg/m3 NDS (respirable dust, containing >50% free crystalline silica); 4.0 mg/m3 NDS (total inhalable dust, containing 2% to 50% free crystalline silica); 1.0 mg/m3 NDS (respirable dust, containing 2% to 50% free crystalline silica) Portugal Romania Slovak Republic 0.05 mg/m3 TWA (respirable fraction) 0.1 fiber/cm3 (Quartz - OEL (8 h) respirable rate) 10 mg/m3 TWA (total aerosol) 0.5 mg/m3 STEL 0.1 mg/m3 TWA 0.15 mg/m3 TWA (respirable fraction) 0.1 mg/m3 VLA-ED (respirable fraction) 5 or 25 k/Q 0.1 mg/m3 LLV (respirable dust) Slovenia Spain Sweden Turkey United Kingdom 0.1mg/m3 If amount of crystalline silica in respirable dust is less than 5%, then the occupational exposure limit will be accepted as 5 mg/m3. If the amount of the crystalline silica in the respirable dust is more than 5% in a workplace, then it is prohibited for such workplace to employ employees for the production. Exposure controls 8.2. 8.2.1. Occupational exposure controls Engineering Controls: Ventilation must be adequate to maintain the ambient workplace atmosphere below the exposure limit(s) outlined in Section 8.1 of this Safety Data Sheet. Respiratory Protection In case of exposure to dust, and in any case if such exposure is above regulatory limits (see above), wear a personal respirator in compliance with national law and European Standard EN 149. Eye / Face Protection: If eye contact while using product may be anticipated, wear appropriate safety glasses with side shields or chemical goggles as described by European Standard EN 166. Skin Protection Wear chemical resistant gloves (such as latex or neoprene) and protective clothing to minimize skin contact. Substance may have drying effect on skin. Maintain good industrial hygiene. Protection recommended for workers suffering from dermatitis or sensitive skin. 8.2.2. Environmental Exposure Controls No special requirements. There is no reported ecotoxicity for silica, a naturally occurring substance abundantly present in nature. Page 6 of 10 U.S. SILICA COMPANY Safety Data Sheet European Union Silica Sand and Ground Silica 9. Physical and Chemical Properties General Information 9.1. 9.2. Physical State: Odor: White or tan sand: granular, crushed or ground to a powder. None Important Health, Safety and Environmental Information pH: Specific Gravity: Melting Point: Freezing Point Boiling Point: Flashpoint: Flammability: Explosive properties: Oxidizing properties: Vapor Pressure: Relative Density: Solubility: 6 - 8 2.65 g/cc 3110°F/1710°C Not Applicable 4046°F/2230°C Not Applicable Not Applicable Not Applicable contact with powerful oxidizing agents such as fluorine, chlorine trifluoride, and oxygen difluoride may cause fires. None Not Applicable Silica will dissolve in hydrofluoric acid and produce a corrosive gas, silicon tetrafluoride Insoluble Water Solubility: Percent Volatiles by Volume: Not Applicable Viscosity: Not Applicable Vapor density: Not Applicable Molecular Weight: 60.08 Evaporation rate: Not Applicable 10. Stability and Reactivity 10.1. Chemical Stability: 10.2. Conditions to Avoid: Stable 10.3. Materials / Chemicals to Be Avoided: 10.4. Hazardous Decomposition Products: 10.5. Hazardous Polymerization: Will not occur. Contact with powerful oxidizing agents such as fluorine, chlorine trifluoride, and oxygen difluoride may cause fires Contact with powerful oxidizing agents, such as fluorine, chlorine trifluoride and oxygen difluoride, may cause fires. Silica will dissolve in hydrofluoric acid and produce the corrosive gas silicon tetrafluoride (SiF4). U.S. SILICA COMPANY Safety Data Sheet European Union Silica Sand and Ground Silica 11. Toxicological Information Page 7 of 10 The method of exposure to crystalline silica that can lead to the adverse health effects described below is inhalation. SILICOSIS A. The major concern is silicosis, caused by the inhalation and retention of respirable crystalline silica dust. Silicosis can exist in several forms, chronic (or ordinary), accelerated, or acute. Chronic or Ordinary Silicosis (often referred to as Simple Silicosis) is the most common form of silicosis, and can occur after many years of exposure to relatively low levels of airborne respirable crystalline silica dust. It is further defined as either simple or complicated silicosis. Simple silicosis is characterized by lung lesions (shown as radiographic opacities) less than 1 centimeter in diameter, primarily in the upper lung zones. Often, simple silicosis is not associated with symptoms, detectable changes in lung function or disability. Simple silicosis may be progressive and may develop into complicated silicosis or progressive massive fibrosis (PMF). Complicated silicosis or PMF is characterized by lung lesions (shown as radiographic opacities) greater than 1 centimeter in diameter. Although there may be no symptoms associated with complicated silicosis or PMF, the symptoms, if present, are shortness of breath, wheezing, cough and sputum production. Complicated silicosis or PMF may be associated with decreased lung function and may be disabling. Advanced complicated silicosis or PMF may lead to death. Advanced complicated silicosis or PMF can result in heart disease secondary to the lung disease (cor pumonale). Accelerated Silicosis can occur with exposure to high concentrations of respirable crystalline silica over a relatively short period; the lung lesions can appear within five (5) years of initial exposure. Progression can be rapid. Accelerated silicosis is similar to chronic or ordinary silicosis, except that lung lesions appear earlier and progression is more rapid. Acute Silicosis can occur with exposures to very high concentrations of respirable crystalline silica over a very short time period, sometimes as short as a few months. The symptoms of acute silicosis include progressive shortness of breath, fever, cough and weight loss. Acute silicosis is fatal. B. IARC - The International Agency for Research on Cancer ("IARC") concluded that there was "sufficient evidence in humans for the carcinogenicity of crystalline silica in the forms of quartz or cristobalite from occupational sources", and that there is "sufficient evidence in experimental animals for the carcinogenicity of quartz and cristobalite." The overall IARC evaluation was that "crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1)." The IARC evaluation noted that "carcinogenicity was not detected in all industrial circumstances studies. Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on external factors affecting its biological activity or distribution of its polymorphs." For further information on the IARC evaluation, see IARC Monographs on the Evaluation of Carcinogenic Risks to Humans, Volume 68,"Silica, Some Silicates..." (1997). The EU Scientific Committee for Occupational Exposure Limits (SCOEL) concluded in June 2002 (SCOEL Sum Doc. 94-final): “The main effect in humans of inhalation of respirable silica dust is silicosis. There is sufficient information to conclude that the relative risk of lung cancer is increased in persons with silicosis (and apparently, not in employees without silicosis exposed to silica dust in quarries and in the ceramic industry). Therefore preventing the onset of silicosis will also reduce the cancer risk.” C. Several studies have reported excess cases of several autoimmune disorders, -- scleroderma, systemic lupus erythematosus, rheumatoid arthritis -- among silica-exposed workers. For a review of the subject, the following may be consulted: “Occupational Exposure to Crystalline Silica and Autoimmune Disease”, Environmental Health Perspectives, Volume 107, Supplement 5, pp. 793-802 (1999); "Occupational Scleroderma", Current Opinion in Rheumatology, Volume 11, pp. 490-494 (1999). AUTOIMMUNE DISEASES CANCER U.S. SILICA COMPANY Safety Data Sheet European Union Silica Sand and Ground Silica Page 8 of 10 TUBERCULOSIS KIDNEY DISEASE NON-MALIGNANT RESPIRATORY DISEASES D. Individuals with silicosis are at increased risk to develop pulmonary tuberculosis, if exposed to persons with tuberculosis. The following may be consulted for further information: Occupational Lung Disorders, Third Edition, Chapter 12, entitled "Silicosis and Related Diseases", Parkes, W. Raymond (1994); "Risk of pulmonary tuberculosis relative to silicosis and exposure to silica dust in South African gold miners," Occup Environ Med., Volume 55, pp.496-502 (1998). E. Several studies have reported excess cases of kidney diseases, including end stage renal disease, among silica-exposed workers. For additional information on the subject, the following may be consulted: "Kidney Disease and Silicosis”, Nephron, Volume 85, pp. 14-19 (2000). F. The reader is referred to Section 3.5 of the NIOSH Special Hazard Review cited below, for information concerning the association between exposure to crystalline silica and chronic bronchitis, emphysema and small airways disease. There are studies that disclose an association between dusts found in various mining occupations and non-malignant respiratory diseases, particularly among smokers. It is unclear whether the observed associations exist only with underlying silicosis, only among smokers, or result from exposure to mineral dusts generally (independent of the presence or absence of crystalline silica, or the level of crystalline silica in the dust). Sources of information: The NIOSH Hazard Review - Occupational Effects of Occupational Exposure to Respirable Crystalline Silica published in April 2002 summarizes and discusses the medical and epidemiological literature on the health risks and diseases associated with occupational exposures to respirable crystalline silica. The NIOSH Hazard Review should be consulted for additional information, and citations to published studies on health risks and diseases associated with occupational exposure to respirable crystalline silica. The NIOSH Hazard Review is available from NIOSH - Publications Dissemination, 4676 Columbia Parkway, Cincinnati, OH 45226, or through the NIOSH web site, www.cdc.gov/niosh/topics/silica, then click on the link “NIOSH Hazard Review: Health Effects of Occupational Exposure to Respirable Crystalline Silica”. Crystalline silica (quartz) is not known to be ecotoxic; i.e., there are no data that suggests that crystalline silica (quartz) is toxic to birds, fish, invertebrates, microorganisms or plants. 12. Ecological Information 12.1. Ecotoxicological Information: 13. Disposal Considerations 13.1. Waste Disposal Method: 13.2. Container Handling and Disposal: Discard any product, residue, disposable container or liner in full compliance with national regulations. Dispose of container and unused contents in accordance with national regulations. U.S. SILICA COMPANY Safety Data Sheet European Union Silica Sand and Ground Silica Page 9 of 10 14. Transportation Information Shipping Name: ADR/RID/IMO/ICAO /US DOT Proper Shipping Name Not Regulated Hazard Class ID Number Not Regulated Not Regulated Packaging Group Not Regulated 15. Regulatory Information Silica sand has no harmonized classification & labeling under Directives 67/548/EEC and 1999/45/EC. Because the respirable fraction is high (10% and more) in ground silica (flour), the preparation is self-classified as Xn (harmful). In such case, the following risk and safety phrases are applicable. Risk Phrases: R 48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation. Safety Phrases: S 22: Do not breathe dust S 38: In case of insufficient ventilation, wear suitable respiratory equipment. Under EC Number 1272/2008 (CLP) regulations, mixtures containing more than 10% crystalline silica, which potentially includes all of the grades listed in the MSDS, there are hazard class, hazard statements and precaution statements: Hazard Class: STOT RE1: Specific Target Organ Toxicant, DANGER Hazard Statement: H372: Causes damage to lungs through prolonged or repeated exposure via inhalation Precaution Statements: P260: Do not breathe dust. P285: In case of inadequate ventilation wear respiratory protection. P501: Dispose of contents / containers in accordance with local regulation. 16. Other Information * For further information on health effects, see Sections 2 and 11 of this Safety Data Sheet. 13 European industry associations and two employee associations concluded on April 25, 2006 an autonomous European Social Dialogue Agreement on “Workers Health Protection through the Good Handling and Use of Crystalline Silica and Products Containing it” which is applicable since October 25, 2006. This Agreement and its annexes provide technical guidance and good handling recommendations for dust prevention. The Agreement and its annexes are available at http://www.nepsi.eu/ U.S. SILICA COMPANY Safety Data Sheet European Union Silica Sand and Ground Silica Page 10 of 10 U. S. Silica Company Disclaimer The information and recommendations contained herein are based upon data believed to be up- to-date and correct. However, no guarantee or warranty of any kind, express or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects that may be caused by purchase, resale, use or exposure to our silica. Customers and users of silica must comply with all applicable health and safety laws, regulations, and orders. In particular, they are under an obligation to carry out a risk assessment for the particular work places and to take adequate risk management measures in accordance with the national implementation legislation of EU Directives 89/391 and 98/24. February 2011 SAFETY DATA SHEET Version No:20-01 Issue Date: 03-Dec-2020 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING SPECTRALOCK® PRO Premium Grout Manufacturer/ Importer/ Supplier/ Distributor information 2. HAZARD (s) IDENTIFICATION Product Name Recommended use Classification Label Element Signal Words Hazard Statement(s) Precautionary Statement(s) Prevention Precautionary Statement(s) Response Precautionary Statement(s) Storage Precautionary Statement(s) Disposal Supplemental information Emergency overview SPECTRALOCK® Pro Premium Grout- Part A It is a multi component, high strength epoxy grout, for joints in tile and stone installations. (For professional use). Company Name: LATICRETE MIDDLE EAST LLC Address P.O. Box. 86028, Ras Al Khaimah, United Arab Emirates Telephone: +971 7 244 6396 Skin corrosion Category 1B Skin Sensitization Category 1 Serious eye damage/eye irritation Category 1 Danger H315- Causes skin irritation H317 -May cause an allergic skin reaction. H318 Causes serious eye irritation. H411-Toxic to aquatic life with long lasting effects. P272 - Contaminated work clothing should not be allowed out of the workplace. P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER/doctor P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P501-Dispose of contents/container in accordance with local/regional/national/international regulations. Harmful to aquatic life with long lasting effects. Avoid release to the environment IRRITANT. Irritating to eyes, respiratory system and skin. Other hazards which do not result in classification None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS Mixtures : Information on ingredients / Hazardous components Name CAS No Content (% by wt.) Poly[oxy(methyl-1,2-1– 4 ethanediyl)], .alpha.-(2-aminometh yleth yl)-.omega .-(2- amino methy lethoxy)- 3,6,9-Triazaundecamethylenediamine Formaldehyde, polymer with N1-(2-aminoethyl)-N2-[2-[(2-aminoethyl)amino]ethyl]-1,2-ethanediamine, 2,2'-[1,4-butanediylbis(oxymethylene)]bis[oxirane], 4,4'-(1-methylethylidene) bis(4,1- phenyleneoxymethylene)bis[oxirane], reaction products with Bu glycidylether and 1-[[2-(2-aminoethyl) ethyl]amino]-3-phenoxy-2-propanol, acetates (salts) 9046-10-0 112-57-2 180583-06-6 1 - 4 < 2 > 15 Page 1 of 5 SPECTRALOCK® Pro Premium Grout- Part A SAFETY DATA SHEET Version No:20-01 Issue Date: 03-Dec-2020 4. FIRST-AID MEASURES Inhalation Skin contact Eye contact Ingestion Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if any discomfort continues Take off immediately all contaminated clothing. Chemical burns must be treated by a physician. Wash contaminated clothing before reuse. Get medical attention immediately Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical attention if any discomfort continues. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Personal protection for first-aid responders Symptoms caused by exposure Up to now no symptoms are known Medical attention and special treatment Provide general supportive measures and treat symptomatically. 5. FIRE-FIGHTING MEASURES Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for fire fighters Firefighting equipment/instructions General fire hazards 6.ACCIDENTAL RELEASE MEASURES For non-emergency personnel Personal precautions, protective equipment and emergency procedures Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO 2). Do not use water jet as an extinguisher, as this will spread the fire May generate ammonia gas. May generate toxic nitrogen oxide gases. Use of water may result in the formation of very toxic aqueous solutions. Do not allow run-off from fire fighting to enter drains or water courses. Incomplete combustion may form carbon monoxide. Ammonia gas may be liberated at high temperatures. In case of incomplete combustion an increased formation of oxides of nitrogen (NOx) is to be expected. Downwind personnel must be evacuated. Burning produces noxious and toxic fumes. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Wear self-contained breathing apparatus for firefighting if necessary. Avoid contact with skin. A face shield should be worn. Do not allow run-off from fire fighting to enter drains or water courses. No unusual fire or explosion hazards noted. Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For emergency responders Wearing appropriate protective clothing. Environmental precautions Methods and materials for containment and cleaning up Avoid release to the environment. Do not discharge into drains, water courses or onto the ground. Environmental manager must be informed of all major releases Large Spills: Pick up with suitable appliance and dispose of. Pack in tightly closed containers for disposal. Small Spills: Pick up with suitable appliance and dispose off. Other issues relating to spills and releases Never return spills in original containers for re-use. For waste disposal, see Section 13 Page 2 of 5 SPECTRALOCK® Pro Premium Grout- Part A 7. HANDLING AND STORAGE Precautions for safe handling SAFETY DATA SHEET Version No:20-01 Issue Date: 03-Dec-2020 of the SDS. Clean up in accordance with all applicable regulations. Use personal protective equipment. Do not use sodium nitrite or other nitrosating agents in formulations containing this product. Suspected cancer-causing nitrosamines could be formed. Avoid contact with skin and eyes. Emergency showers and eye wash stations should be readily accessible. Adhere to work practice rules established by government regulations. Avoid contact with eyes. Hygiene measures: Provide readily accessible eye wash stations and safety showers. General protective measures: Discard contaminated leather articles. Provide readily accessible eye wash stations and safety showers. Wash hands at the end of each work shift and before eating, smoking or using the toilet. Conditions for safe storage, including any incompatibilities Containers should be stored tightly sealed in a dry place. Do not store near acids. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Occupational exposure limits Biological limit values Appropriate engineering controls No Data Available No Data Available Individual protection measures, for example personal protective equipment (PPE) No biological exposure limits noted for the ingredient(s). Good general ventilation should be used. Provide eyewash station. Eye/face protection Wear safety glasses with side shields (or goggles). Face-shield. Wear a full- face respirator, if needed Skin protection Hand protection Wear appropriate chemical resistant gloves. Others Respiratory protection Hygiene measures Body protection must be chosen based on level of activity and exposure. In case of insufficient ventilation, wear suitable respiratory equipment Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants Page 3 of 5 SPECTRALOCK® Pro Premium Grout- Part A SAFETY DATA SHEET Version No:20-01 Issue Date: 03-Dec-2020 10. STABILITY AND REACTIVITY Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Corrosive to certain metals. Copper Aluminum. Zinc. Material is stable under normal conditions Viscous Liquid Yellow to Amber Typical Not applicable Not applicable >1000C Not flammable Not applicable Not flammable Not applicable 1.10 Dispersible in water Not available Heat, flame 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour Odour pH Melting point/ freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Vapor pressure Relative density Solubility (water) Auto-ignition temperature Reactivity Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products 11. TOXICOLOGICAL INFORMATION Information on possible routes of exposure Acute toxicity/ Effects Oral Inhalation Dermal Eye Sensitization CAUTION! N-Nitrosamines, many of which are known to be potent carcinogens, may be formed when the product comes in contact with nitrous acid, nitrites or atmospheres with high nitrous oxide concentrations. Nitrous acid and other nitrosating agents, Organic acids (i.e. acetic acid, citric acid etc.). Mineral acids. sodium hypochlorite, Oxidizing agents Reaction with peroxides may result in violent decomposition of peroxide possibly creating an explosion. Product slowly corrodes copper, aluminum, zinc and galvanized surfaces. Nitric acid, Ammonia, Nitrogen oxides (NOx) Nitrogen oxide can react with water vapors to form corrosive nitric acid. Carbon monoxide, Carbon dioxide (CO2) Nitrosamine Chlorine Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquid. May cause discomfort if swallowed. LD50, Species: Rat, Dose: 2.1 g/kg, May cause respiratory irritation LD50 Species: Rat, Dose: 2.0 g/kg, No death observed Causes eye irritation on direct contact May cause sensitization by skin contact Page 4 of 5 SPECTRALOCK® Pro Premium Grout- Part A Chronic Toxicity /Effects Carcinogenicity Reproductive toxicity Aspiration hazard Other Information 12. ECOLOGICAL INFORMATION Aquatic-toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Additional information 13. DISPOSAL CONSIDERATIONS Disposal methods Residual waste Contaminated packaging 14. TRANSPORT INFORMATION IMDG IATA/ ICAO SAFETY DATA SHEET Version No:20-01 Issue Date: 03-Dec-2020 This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA No classified Not classified Nil. Harmful to aquatic life with long lasting effects No data is available on the degradability of this product. No data available. No data available. Do not allow to enter soil, waterways or waste water canal. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local / regional/ national/ international regulations. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Completely emptied packaging can be given for recycling. UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Tetraethylenepentamine) Class : 9 Packing group : III UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Tetraethylenepentamine) Class : 9 Packing group : III 15. REGULATORY INFORMATION Safety, health and environmental regulations National regulations Followed International regulations 16. OTHER INFORMATION EINECS: All ingredients listed, exempt or notified (ELINCS). TSCA: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. AICS: All ingredients listed, exempt or notified. IECSC: All ingredients listed or exempt. KECL: All ingredients listed, exempt or notified. PICCS: All ingredients listed, exempt or notified. DSL: All ingredients listed or exempt. Issue date Disclaimer: The information in this (M) SDS was obtained from sources which we believe are reliable but cannot guarantee. Additionally, your use of this information is beyond our control and may be beyond our knowledge. Therefore, the information is provided without any representation or warranty express or implied. 03-December-2020 /JC Page 5 of 5 SPECTRALOCK® Pro Premium Grout- Part A MATERIAL SAFETY DATA SHEET CONTACT NUMBERS: 1(800) 452-4862 FAX 1-626-333-7694 CHEMTREC (24-hrs): (800) 424-9300 Section I: Product Information Identity: Trade Names: SPODUMENE Spodumene Mixture of naturally occurring silicates and quartz. Prepared/Revised: 8/2012 Section II: Hazardous Ingredients Chemical Name: CAS # Spodumene (LiAl(SiO3)2 1302-37-0 10 mg/m3 Quartz (SiO2) 14808-60-7 10 mg/m3 / %SiO2 +2 0.05 0.05 95 <5% OSHA PEL ACGIH TLV Percent Section III: Physical Data Boiling Point: Vapor Pressure (mm/Hg): Vapor Density (Air=1): Solubility in Water: Appearance and Odor: Specific Gravity (H2O=1): Melting Point: Evaporation Rate (Butyl Acetate=1): NA NA NA < 0.5% White to beige powder, Odorless 3.1 1375C NA Section IV: Fire and Explosion Hazard Data Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Not combustible LEL NA As appropriate for surrounding combustibles. In the event of fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Not combustible. UEL NA 0 1 0 Section V: Reactivity Data Stability: Conditions to Avoid: Incompatibility (materials to avoid): Hazardous Decomposition or Byproducts: Hazardous Polymerization: Stable under ordinary conditions of use and storage. None known. None known. None known. Will not occur. Page 1 of 2 www.Lagunaclay.com800-452-4862info@lagunaclay.comSection VII: Precautions for Safe Handling and Use Material Release or Spill Precautions: INHALATION: May cause irritation of mucous membrane if dust is inhaled over a prolonged period of time. Prolonged exposure to silica dust may result in silicosis, a fibrotic lung disease. SKIN: No. INGESTION: Ingestion of mineral compounds may cause abdominal pain and nausea. Respiratory disease may result from prolonged overexposure. Can cause eye irritation. NTP: Yes (Silica) IARC Monographs: Yes (Silica) Excessive inhalation of dust may result in shortness of breath and reduced pulmonary function. Symptoms of silicosis include impaired pulmonary function and wheezing. Persons with impaired respiratory function may be more susceptible to the effect of this substance. IF INHALED, remove to fresh air and seek medical attention for any breathing difficulty. IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. IN CASE OF EYE CONTACT, flush eyes immediately with water for at least 15 minutes. Seek medical attention if irritation persists. IF INGESTED, induce vomiting immediately by giving two glasses of water and sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. Should a spill occur, ventilate area. Clean-up personnel require respiratory protection. Recover uncontaminated material for use. Vacuum or sweep remaining material, keeping dust to a minimum. Dispose of un-reclaimable material in a RCRA-approved waste facility. Protect containers from damage and keep closed when not in use. Observe good personal hygiene. Wash after handling. Use NIOSH approved particulate respirator if dust generation occurs or is anticipated. OSHA standard 1910.134 or ANSI Z88.2- 1980 specifications are recommended. A system of local and/or general exhaust is recommended to keep employee exposures below the airborne exposure limits. Local exhaust is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, “Industrial Ventilation, A Manual of Recommended Practices”, most recent edition, for details. Yes Safety goggles are recommended. Use other protective equipment when necessary in order to avoid prolonged exposure to skin. Observe good personal hygiene. Wash after handling. Section VI: Health Hazard Data Route of Entry: Health Hazards (Acute and Chronic): Carcinogenicity: Signs and Symptoms of Exposure: Aggravation of Pre-existing Conditions: Emergency and First Aid Procedures: Waste Disposal Method: Handling and Storing Precautions: Other Precautions: Section VIII: Control Measures Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Other Protective Clothing or Equipment: Work and Hygienic Practices: Page 2 of 2 www.Lagunaclay.com800-452-4862info@lagunaclay.com SAFETY DATA SHEET Issue Date 01/01/15 Revision Date 02/10/21 Version 3 1 IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND COMPANY UNDERTAKING World’s Best Graffiti Coating Urban Restoration Group US Inc. 5439 San Fernando Rd. W Los Angeles CA 90039 24-Hour Emergency Telephone Number: (PERS) Professional Emergency Resource Services USA 1-800-633-8253 (Int'l 1-801-629-0667) Contract number: 8400 Product Name: Company: Phone Number: Fax: Intended Use: 1- 818- 247- 2555 1- 818- 247- 2515 All-weather, long-term SACRIFICIAL protection, formulated for most types of surfaces. Provides durable protection against spray paint, marker / felt tip pens, pollution and grime. Also provides protection against salt and sea type moisture. 2 HAZARDS IDENTIFICATION Classification of the substance or mixture: Eye irritation, hazard Category 2 Signal Word: WARNING Hazard Statement: H319 Causes serious eye irritation. Precautionary Statements: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/attention. 3 COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Ingredients CAS Number Percentage Range Alcohols, C12-15, branched and linear, ethoxylated 106232-83-1 (Z)-9-Octadecen-1-ol ethoxylated Alcohols, C16-18, ethoxylated 9004-98-2 68439-49-6 Sodium hydroxide 1310-73-2 <1% <0.5% <0.5% <0.5% Balance – Trade Secret The complete specific chemical identity has been withheld as a trade secret. Other ingredients are not known to significantly contribute to the hazard classification. Page 1 of 5 World’s Best Graffiti Coating 4 FIRST-AID MEASURES Revision Date 02/10/21 As a general rule, in case of doubt or if symptoms persist, always call a doctor. NEVER induce swallowing by an unconscious person. Inhalation: Skin contact: Eye contact: Ingestion: No significant risk Rinse with water IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Drink a couple of glasses of water. If symptoms persist, call a physician 5 FIRE-FIGHTING MEASURES Extinguishing Media Fire can be extinguished using: Special hazards arising from the substance or mixture: Water Not applicable Protective Equipment for firefighting: In the event of fire, wear self contained breathing apparatus. Wear suitable protective clothing 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Not applicable Environmental Precautions: Prevent large discharges to drains. Bank up and collect Methods for Cleaning Up: Only large-scale discharges can constitute a risk. Collect spillages as soon as possible by using an absorbent material. Rinse clean with plenty of water. Consider the risk of slipping 7 HANDLING AND STORAGE Handling: Do not get in eyes. Wash hands before eating, drinking, or smoking. Ensure good industrial hygiene Storage: The package must be stored sealed and in a cool location. Page 2 of 5 World’s Best Graffiti Coating Revision Date 02/10/21 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational Exposure Limits: ACGIH TLV (American Conference of Governmental Industrial Hygienists, Threshold Limit Values, 2010) : CAS TWA : STEL : Ceiling : Definition : Criteria : 106232-83-1 N/A N/A N/A 9004-98-2 N/A N/A N/A 68439-49-6 N/A N/A N/A N/A N/A N/A N/A N/A N/A 1310-73-2 2 mg / m³ N/A C N/A N/A Eye / face protection: Safety gloves: Other skin protection: Respiratory protection: Wear protective goggles if there is a risk of direct contact or splashes. No special safety precautions are required. Remove and wash contaminated clothing before re-use. Breathing protection is not normally required. 9 PHYSICAL AND CHEMICAL PROPERTIES Typical values – does not constitute a specification Appearance / Physical State Odor Boiling point/range Flash Point (Abel closed cup) PH Flammability auto ignition temp. Melting point / Freezing point Explosive properties Oxidizing properties Vapor pressure (mbar @ 20°C) Relative Density (@15.5°C) Solubility in water Solubility in fat / solvent Partition coefficient (log Pow) Auto – Ignition temperature Decomposition temperature Viscosity (mPa.s @ 20°C) Evaporation rate White / Liquid Slight odor < 100°C / 212°F Not applicable 8.0 Not applicable 80 - 85 °C / 176 - 185°F Not applicable Not applicable Not applicable Not applicable 100% Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable 10 STABILITY AND REACTIVITY Reactivity: Stability: Conditions to avoid: Materials to avoid: Hazardous decomposition products: Not applicable Not applicable Avoid extreme temperatures during storage. Not applicable Not applicable Page 3 of 5 World’s Best Graffiti Coating Revision Date 02/10/21 The product has a low toxicity, which means that the risk of injury during normal handling is small. 11 TOXICOLOGICAL INFORMATION Information on toxicological effects Acute Toxicity: Not applicable -oral -inhalation -dermal -eye -skin -respiratory tract Corrosivity / Irritation: Causes serious eye irritation Sensitization: -skin -respiratory No evidence of sensitization effects No evidence of sensitization effects 12 ECOLOGICAL INFORMATION Toxicity Acute Fish Toxicity Mixtures Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vPvB assessment No data available. No data available. Other adverse effects The product has a low level of toxicity to aquatic organisms. Sodium Hydroxide (LC50): (96 h) 45 mg/l - This product is easily biodegradable. Bio-accumulation is unlikely. Not applicable. 13 DISPOSAL CONSIDERATIONS Waste treatment methods: Do not pour into drains, sewers or waterways. Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air, soil, plants or animals. Recycle or dispose of waste in compliance with Federal, State, and Local regulations. Appropriate packaging: Dispose of in original packaging or over pack in larger container such as an appropriate 55 gal drum. Give to a certified licensed disposal contractor. Page 4 of 5 W orld’s Best Graffiti Coating Revision Date 02/10/21 14 TRANSPORT INFORMATION UN number UN proper shipping name Transport hazard class Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not regulated Not applicable Not applicable Not applicable Not applicable Not applicable 15 REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 (PROPOSITION 65) N/A This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins under California Proposition 65 at levels which would be subject to the proposition. Any waste generated must comply with Federal EPA and California DTSC regulations pertaining to proper hazardous waste disposal. Additionally comply with all Federal, State and Local regulations. 16 OTHER INFORMATION This product safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. The information identified in this Safety Data Sheet is true and correct based on best knowledge of information available. Revision Date: 02/10/21 Page 5 of 5 Conservation Review Form CITY OF AUSTIN AIPP Exhibit F Information captured in this form will help expedite the conservation review process, which aims to address the following considerations: 1) Durability of Materials 2) Appropriateness of Fabrication Methods 3) Relationship to Site/Context 4) Installation and Site Preparation 5) Maintenance Needs Artist(s): Phone: Email: Title of AIPP Project: Title of Artwork: AIPP Project Manager: Date: Assuming best maintenance practices, what is the life expectancy of this work? List ALL materials and components to be used in the creation of this piece (be specific): Describe any coatings or sealants to be used (be specific): Provide contact information for the fabricator(s) and a description of their services on this project: Rev. Jan 2013 Page | 1 Conservation Review Form CITY OF AUSTIN AIPP Describe the methods and/or processes used in fabrication, in order of their use in the artwork: Describe the artwork site and installation method: Describe any required maintenance procedures and/or products: N Attach all that apply: Y Y Y Y N N N Architect’s or Engineer’s preliminary drawings Material samples Images of site or site drawings Manufacturer specs or Material Data Safety Sheets (MSDS) for all commercial products Rev. Jan 2013 Page | 2 CITY OF AUSTIN ART IN PUBLIC PLACES PROGRAM/CULTURAL ARTS DIVISION USER DEPARTMENT PUBLIC ART EVALUATION FORM FOR TECHNICAL FEASIBILITY AND MAINTENANCE As per Section IX.A of the AIPP Guidelines, the user and managing departments responsible for housing the artwork are requested to review the artist’s final design (attached) for technical feasibility and maintenance considerations. Please provide a response on this form, or on letterhead signed by a representative in your department. Thank you! Department Artwork Title/Description Evaluation Date Evaluator’s Name Title EVALUATOR’S COMMENTS SITE INSTALLATION SAFETY / LIABILITY MAINTENANCE OTHER COMMENTS DEPARTMENTAL RECOMMENDATION (Attach additional sheets as necessary) Support artwork as proposed Signature: Support artwork with the following modification(s): User Department Director or designee Date: Artist Maintenance Questionnaire CITY OF AUSTIN-- AIPP Information captured in this questionnaire will be filed to help ensure the proper care and preservation of the artwork. You may reference the Conservation Review Form as you complete this questionnaire. Please be as specific as possible. (Attach additional sheets as needed) (This section to be completed by AIPP staff) Acc. #: Artist: Dana Perrotti Title: Milagros Date created: TBD 2024 Medium: Ceramic Tiles Dimensions: South Wall: 23.25" x 293.5" North Wall:23.25" x 183.75" Date of Acq: General Information: General description of artwork: (cid:38)(cid:72)(cid:85)(cid:68)(cid:80)(cid:76)(cid:70)(cid:3)(cid:80)(cid:82)(cid:86)(cid:68)(cid:76)(cid:70)(cid:3)(cid:85)(cid:72)(cid:79)(cid:76)(cid:72)(cid:73)(cid:3)(cid:80)(cid:68)(cid:71)(cid:72)(cid:3)(cid:82)(cid:73)(cid:3)(cid:3)(cid:54)(cid:87)(cid:68)(cid:81)(cid:71)(cid:68)(cid:85)(cid:71)(cid:3)(cid:23)(cid:21)(cid:19)(cid:3)(cid:54)(cid:70)(cid:88)(cid:79)(cid:83)(cid:87)(cid:88)(cid:85)(cid:72)(cid:3)(cid:38)(cid:79)(cid:68)(cid:92)(cid:3)(cid:68)(cid:81)(cid:71)(cid:3)(cid:45)(cid:82)(cid:75)(cid:81)(cid:182)(cid:86)(cid:3)(cid:38)(cid:82)(cid:81)(cid:72)(cid:3)(cid:20)(cid:19)(cid:91)(cid:20)(cid:20)(cid:3)(cid:74)(cid:79)(cid:68)(cid:93)(cid:72)(cid:17)(cid:3)(cid:20)(cid:20)(cid:23)(cid:3)(cid:87)(cid:76)(cid:79)(cid:72)(cid:86)(cid:3) (cid:70)(cid:85)(cid:72)(cid:68)(cid:87)(cid:72)(cid:3)(cid:87)(cid:75)(cid:72)(cid:3)(cid:73)(cid:88)(cid:79)(cid:79)(cid:3)(cid:80)(cid:82)(cid:86)(cid:68)(cid:76)(cid:70)(cid:3)(cid:88)(cid:87)(cid:76)(cid:79)(cid:76)(cid:93)(cid:76)(cid:81)(cid:74)(cid:3)(cid:27)(cid:3)(cid:70)(cid:82)(cid:79)(cid:82)(cid:85)(cid:86)(cid:17)(cid:3)(cid:55)(cid:75)(cid:72)(cid:3)(cid:48)(cid:76)(cid:79)(cid:68)(cid:74)(cid:85)(cid:82)(cid:86)(cid:3)(cid:85)(cid:72)(cid:79)(cid:76)(cid:72)(cid:73)(cid:3)(cid:87)(cid:76)(cid:79)(cid:72)(cid:86)(cid:3)(cid:68)(cid:85)(cid:72)(cid:3)(cid:26)(cid:17)(cid:24)(cid:180)(cid:91)(cid:26)(cid:17)(cid:24)(cid:180)(cid:3)(cid:72)(cid:68)(cid:70)(cid:75)(cid:3)(cid:90)(cid:76)(cid:87)(cid:75)(cid:3)(cid:68)(cid:3)(cid:242)(cid:180)(cid:3)(cid:74)(cid:85)(cid:82)(cid:88)(cid:87)(cid:3) (cid:69)(cid:82)(cid:85)(cid:71)(cid:72)(cid:85)(cid:17) Do you have similar work (materials and techniques) in other collections? If so please provide the name/ owner of the collections. Materials and techniques: Please list ALL final materials used in the creation of the piece: See Attached Documents Please list (or attach) manufacturer info for all products used in the final work: See Attached documents If cast or commercially fabricated, please provide information about the factory or foundry: N/A EXHIBIT C - Artist Maintenance Questionnaire Please describe the reasons for selecting the final materials used: Please describe the method of creating the piece (describe special tools, methods, order of application, etc.): Please describe any coatings used: Please provide samples of materials, or documentation of materials and techniques employed: Samples attached (Circle one) YES NO Please describe any special needs (electricity, water, etc) or instructions for the installation of this piece: N/A N/A Please describe any media components used in this piece. Please complete attached Media Checklist. Preservation: Please share any opinions or recommendations regarding preventative preservation treatments. Please describe the extent to which changes in the appearance of the piece (as a result of aging and wear- and-tear) are intended/ accepted. How would you define damage? The tiles are expected to last 50 years. The glaze has been tested to prevent crazing or cracking. The colors will gradually fade after many years of UV exposure from the sun but it will be minimal and inline with the existing mosaic work on site. Please share your opinions on interventions; the condition at which an intervention should be considered; the extent to which the intervention is intended/ accepted: Though unlikely, if a tile needs to be replaced, a new tile can be cast and set into the mural. EXHIBIT C - Artist Maintenance Questionnaire Please list the frequency of cleaning or care needed, with specific techniques and/or products to be used. Please be detailed in the brand name or manufacturers’ specifications of products you would recommend, as well as step-by-step instructions for care. Spray down the wall once a year with a hose to wash away loose dirt and debris. Do not wash with a power washer. Signature Date EXHIBIT C - Artist Maintenance Questionnaire BUDGET Artist Design + Project Management Fee (20%): $8600 Fabrication: Studio Rental Fees– Studio $300x6=$1800 Kiln Firings $2030 Fabrication of Ceramic tiles: (Sculpt Masters/Make Molds/Press Molds/Glaze/Fire)- $14,600 Community Outreach Workshops: $200/hr (instructing time only–prep included). Three workshops @ 4 hours total =$750 Art Storage–$505 TOTAL –$19685 Materials + Supplies: 2000 lbs Standard 420 Stoneware + Freight–$1825 Glaze Materials (Dry) $900 Plaster $450 Tile Setters $450 Thin-set $500 Grout $300 Anti-graffiti sealant $950 Misc (Cottle Boards/Oil Soap; Tools/Materials for workshops; Buckets for glazes; Trowels; Cleaning Supplies; Wire Racks; Bubble wrap/Corrugated Cardboard/Boxes)--$1250 TOTAL–$5460 Installation: $3000 Insurance: General Liability & Fine Arts Floater: $500 Auto Liability: $600 TOTAL-$1100 Photography and Documentation of work: $1000 Contingency (8%): $3440 TOTAL $43,000 • Community Engagement begins (Main engagement will be during fabrication for D. Perrotti) Comal Pocket Park Art in Public Places Project Schedule Updated: January 10, 2024 • Design contract executed • Kickoff Meeting March – April • Concept and Initial Design • Mid-Design review and approval 2023 February March May September 2024 January March • Final Design approval – AIPP Panel (Sept. 4, 2023) • Final Design approval – Arts Commission (Sept. 18, 2023) August – October • Fabrication Begins • Modified Final Design approval– AIPP Panel (Jan. 8, 2023) • Modified Final Design approval – Arts Commission (Jan. 29, 2023) • Fabrication Complete • May Installation begins on-site • Anticipated project completion based on PARD construction schedule